[L 2 Fe(μ‐OH)(μ‐CH 3 CO 2 ) 2 ](ClO 4 )·H 2 O, a Model Compound for the Diiron Centers in Deoxyhemerythrin
1985; Wiley; Volume: 24; Issue: 9 Linguagem: Inglês
10.1002/anie.198507781
ISSN1521-3773
AutoresPhalguni Chaudhury, Karl Wieghardt, Bernhard Nuber, Johannes Weiß,
Tópico(s)Metal-Catalyzed Oxygenation Mechanisms
ResumoThe active center of deoxyhemerythrin and the title compound 1 have similar structures and similar magnetic and spectroscopic properties. In both cases, two Fe II centers are bridged by two carboxylato ligands and one hydroxo ligand. equation image
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