Yb(OTf)3–TMSOTf-catalyzed reactions of acylzirconocene chloride to imines
2001; Elsevier BV; Volume: 42; Issue: 8 Linguagem: Inglês
10.1016/s0040-4039(00)02282-6
ISSN1873-3581
AutoresAkito Kakuuchi, Takeo Taguchi, Yuji Hanzawa,
Tópico(s)Chemical Synthesis and Analysis
ResumoDirect access of α-amino ketone derivatives through reactions of acylzirconocene chlorides with derivatives of N-benzylideneaniline, in which acylzirconocene chlorides react as an ‘unmasked’ acyl anion donor, was carried out for the first time under Yb(OTf)3–TMSOTf-catalyzed conditions.
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