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Photo-stabilization properties of transparent inorganic UV-filter/epoxy nanocomposites

2007; Elsevier BV; Volume: 67; Issue: 15-16 Linguagem: Inglês

10.1016/j.compscitech.2007.03.010

1879-1050

Yuan‐Qing Li, Yang Yang, Shao‐Yun Fu,

Skin Protection and Aging

Transparent inorganic UV-filter/epoxy nanocomposites with high photo-stabilization properties were reported in this paper. First, inorganic UV-filter ZnO, core-shell structural silica–titania (S–T) and silica–titania–silica (S–T–S) nanoparticles were synthesized. Transparent inorganic UV-filter/epoxy (ZnO/epoxy, S–T/epoxy and S–T–S/epoxy) nanocomposites were subsequently prepared from the transparent epoxy and the as-prepared nanoparticles via in situ polymerization method. Optical properties of inorganic UV-filter/epoxy nanocomposites, namely visible light transparency and UV-light shielding efficiency, were studied using an UV–Vis spectrophotometer. The photo-stabilization properties of inorganic UV-filter/epoxy nanocomposites were examined by the light-emitting diode (LED) lifetime test. The results showed that the photo-stabilization effect of inorganic UV-filter on the lifetime of LED lamp obeys the following sequence: ZnO > S–T–S > S–T. Compared with the UV LED lamps encapsulated with pure epoxy, the lifetime of UV LED lamps encapsulated with ZnO/epoxy, S–T–S/epoxy and S–T/epoxy nanocomposites has been improved by 76%, 54% and 33%, respectively.