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Atropisomeric phosphinines: design and synthesis

2007; Royal Society of Chemistry; Issue: 46 Linguagem: Inglês

10.1039/b715197g

1477-9234

Christian Müller, Evgeny A. Pidko, D. Totev, Martin Lutz, Anthony L. Spek, Rutger A. van Santen, Dieter Vogt,

Molecular spectroscopy and chirality

The first atropisomeric phosphinine was designed and prepared by introducing substituents into specific positions of the heterocyclic framework; the presence of axial chirality was predicted by means of DFT calculations and experimentally verified by chiral HPLC analysis, derivatization experiments as well as temperature dependent 31P{1H} NMR spectroscopy.