Radical or Not Radical: Revisiting Lithium–Sulfur Electrochemistry in Nonaqueous Electrolytes
2015; Wiley; Volume: 5; Issue: 16 Linguagem: Inglês
10.1002/aenm.201401801
ISSN1614-6840
AutoresMarine Cuisinier, Connor J. Hart, Mahalingam Balasubramanian, Arnd Garsuch, Linda F. Nazar,
Tópico(s)Advancements in Battery Materials
ResumoTracking down trisulfur radical in lithium–sulfur batteries is reported. In nonaqueous electrolytes, dissociation of polysulfide dianions to radicals, and particularly trisulfur S3·−, is believed to play a key role in the performance of lithium sulfur batteries. While S3·− exists in only minor concentration in glymes, exacerbated dissociation in donor solvents allows full utilization of both sulfur and lithium sulfide. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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