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Copper-free click chemistry for the in situ crosslinking of photodegradable star polymers

2008; Royal Society of Chemistry; Issue: 26 Linguagem: Inglês

10.1039/b803043j

1364-548X

Jeremiah A. Johnson, Jeremy M. Baskin, Carolyn R. Bertozzi, Jeffrey T. Koberstein, Nicholas J. Turro,

Chemical Synthesis and Analysis

Bifunctional, fluorinated cyclooctynes were used for the in situ "click" crosslinking of azide-terminated photodegradable star polymers, yielding photodegradable polymeric model networks with well-defined structures and tunable gelation times.