A Matrix‐Isolation and Quantum‐Chemical Investigation of FeF 4
2012; Wiley; Volume: 51; Issue: 48 Linguagem: Inglês
10.1002/anie.201206464
ISSN1521-3773
AutoresTobias Schlöder, Thomas Vent‐Schmidt, Sebastian Riedel,
Tópico(s)Inorganic Fluorides and Related Compounds
ResumoAngewandte Chemie International EditionVolume 51, Issue 48 p. 12063-12067 Communication A Matrix-Isolation and Quantum-Chemical Investigation of FeF4† Tobias Schlöder, Tobias Schlöder Albert-Ludwigs-Universität Freiburg, Institut für Anorganische und Analytische Chemie, Albertstrasse 21, 79104 Freiburg (Deutschland) http://www.psichem.deSearch for more papers by this authorThomas Vent-Schmidt, Thomas Vent-Schmidt Albert-Ludwigs-Universität Freiburg, Institut für Anorganische und Analytische Chemie, Albertstrasse 21, 79104 Freiburg (Deutschland) http://www.psichem.deSearch for more papers by this authorDr. Sebastian Riedel, Corresponding Author Dr. Sebastian Riedel [email protected] Albert-Ludwigs-Universität Freiburg, Institut für Anorganische und Analytische Chemie, Albertstrasse 21, 79104 Freiburg (Deutschland) http://www.psichem.deAlbert-Ludwigs-Universität Freiburg, Institut für Anorganische und Analytische Chemie, Albertstrasse 21, 79104 Freiburg (Deutschland) http://www.psichem.deSearch for more papers by this author Tobias Schlöder, Tobias Schlöder Albert-Ludwigs-Universität Freiburg, Institut für Anorganische und Analytische Chemie, Albertstrasse 21, 79104 Freiburg (Deutschland) http://www.psichem.deSearch for more papers by this authorThomas Vent-Schmidt, Thomas Vent-Schmidt Albert-Ludwigs-Universität Freiburg, Institut für Anorganische und Analytische Chemie, Albertstrasse 21, 79104 Freiburg (Deutschland) http://www.psichem.deSearch for more papers by this authorDr. Sebastian Riedel, Corresponding Author Dr. Sebastian Riedel [email protected] Albert-Ludwigs-Universität Freiburg, Institut für Anorganische und Analytische Chemie, Albertstrasse 21, 79104 Freiburg (Deutschland) http://www.psichem.deAlbert-Ludwigs-Universität Freiburg, Institut für Anorganische und Analytische Chemie, Albertstrasse 21, 79104 Freiburg (Deutschland) http://www.psichem.deSearch for more papers by this author First published: 24 October 2012 https://doi.org/10.1002/anie.201206464Citations: 34 † This work has been supported by the DFG project HA 5639/3-1 and the Fonds der Chemischen Industrie (FCI). We are grateful to the BWGrid cluster for providing computational resources and to Dr. Eicher from the Solvay Fluor GmbH for generous support with F2. We thank C. Roll, R. Tomm, and M. Melder from the technical workshop of the chemistry department for their help with the construction of the matrix chamber and the laser-ablation setup. We are also grateful to Prof. Ingo Krossing and Prof. Harald Hillebrecht for their generous and continuous support. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Beyond iron trifluoride: Matrix-isolation IR spectroscopy and state-of-the-art quantum-chemical calculations have led to the characterization of iron tetrafluoride, a previously unknown species. FeF4 has been prepared by co-deposition of laser-ablated iron atoms with fluorine under excess of noble gases (neon and argon) at cryogenic temperatures. Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201206464_sm_miscellaneous_information.pdf155.5 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. 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