Artigo Acesso aberto Revisado por pares

Influence of Photon Excess Energy on Charge Carrier Dynamics in a Polymer‐Fullerene Solar Cell

2012; Wiley; Volume: 2; Issue: 9 Linguagem: Inglês

10.1002/aenm.201200030

ISSN

1614-6840

Autores

Tom G. J. van der Hofstad, Daniele Di Nuzzo, Mauricio van den Berg, René A. J. Janssen, Stefan C. J. Meskers,

Tópico(s)

Force Microscopy Techniques and Applications

Resumo

Advanced Energy MaterialsVolume 2, Issue 9 p. 1095-1099 Communication Influence of Photon Excess Energy on Charge Carrier Dynamics in a Polymer-Fullerene Solar Cell Tom G. J. van der Hofstad, Tom G. J. van der Hofstad Molecular Materials and Nanosystems, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, The NetherlandsSearch for more papers by this authorDaniele Di Nuzzo, Daniele Di Nuzzo Molecular Materials and Nanosystems, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, The NetherlandsSearch for more papers by this authorMauricio van den Berg, Mauricio van den Berg Molecular Materials and Nanosystems, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, The NetherlandsSearch for more papers by this authorRené A. J. Janssen, René A. J. Janssen Molecular Materials and Nanosystems, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, The NetherlandsSearch for more papers by this authorStefan C. J. Meskers, Corresponding Author Stefan C. J. Meskers [email protected] Molecular Materials and Nanosystems, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, The NetherlandsMolecular Materials and Nanosystems, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, The Netherlands.Search for more papers by this author Tom G. J. van der Hofstad, Tom G. J. van der Hofstad Molecular Materials and Nanosystems, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, The NetherlandsSearch for more papers by this authorDaniele Di Nuzzo, Daniele Di Nuzzo Molecular Materials and Nanosystems, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, The NetherlandsSearch for more papers by this authorMauricio van den Berg, Mauricio van den Berg Molecular Materials and Nanosystems, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, The NetherlandsSearch for more papers by this authorRené A. J. Janssen, René A. J. Janssen Molecular Materials and Nanosystems, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, The NetherlandsSearch for more papers by this authorStefan C. J. Meskers, Corresponding Author Stefan C. J. Meskers [email protected] Molecular Materials and Nanosystems, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, The NetherlandsMolecular Materials and Nanosystems, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, The Netherlands.Search for more papers by this author First published: 07 May 2012 https://doi.org/10.1002/aenm.201200030Citations: 67Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Optical excitation of a polymer-fullerene solar cell via the charge-transfer transition at the donor-acceptor interface, leads to generation of charge carriers displaying dynamics that are indistinguishable from those generated by excitation of the conjugated polymer at higher photon energy. This indicates that excess energy liberated in the photoinduced electron transfer between polymer and fullerene is not essential for the charge carrier generation. References 1 M. Hallermann, S. Haneder, E. Da Como, Appl. Phys. Lett. 2008, 93, 053307. 2 S. Gélinas, O. Paré-Labrosse, C. N. Brosseau, S. A. Seifried, C. R. McNeill, K. R. Kirov, I. A. Howard, R. Leonelli, R. H. Friend, C. Silva, J. Phys. Chem. C 2011, 115, 7114. 3 M. Muntwiler, Q. Yang, W. A. Tisdale, X.-Y. Zhu, Phys. Rev. Lett. 2008, 101, 196403. 4 J. Kern, S. Schwab, C. Deibel, V. Dyakonov, Phys. Stat. Sol. RRL 2011, 5, 364. 5 D. 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