Rh(I)-Catalyzed Silylation of Aryl and Alkenyl Cyanides Involving the Cleavage of C−C and Si−Si Bonds
2006; American Chemical Society; Volume: 128; Issue: 25 Linguagem: Inglês
10.1021/ja062745w
ISSN1943-2984
AutoresMamoru Tobisu, Yusuke Kita, Naoto Chatani,
Tópico(s)Organoboron and organosilicon chemistry
ResumoThe Rh(I)-catalyzed silylation of nitriles with disilanes is described. The cleavage of inert carbon-cyano and silicon-silicon bonds occurs in this catalysis.
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