Structural Diversity in Alkali Metal Phospholides: A Kalocene‐Type Structure
1996; Wiley; Volume: 35; Issue: 10 Linguagem: Inglês
10.1002/anie.199611251
ISSN1521-3773
AutoresFrédéric Paul, Duncan Carmichael, Louis Ricard, François Mathey,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoPhospholide anions can stabilize unusual structures, for example the first crystallographically characterized derivative of “kalocene” (structural formula on the right). Counterion: [K([18]crown-6)(THF)2]+.
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