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Artigo Acesso aberto Revisado por pares
BIBTEX RIS

Incorporation of Vinyl Chloride in Insertion Polymerization

2013; Wiley; Volume: 52; Issue: 14 Linguagem: Inglês

10.1002/anie.201209724

ISSN

1521-3773

Autores

Hannes Leicht, Inigo Göttker‐Schnetmann, Stefan Mecking,

Tópico(s)

Asymmetric Hydrogenation and Catalysis

Resumo

A palladium-catalyzed insertion copolymerization of vinyl chloride (VC) and ethylene gave chlorinated polyethylene with CH3CHCl(CH2)n units (see scheme; C blue, O red, Pd orange, S yellow). The CH3CHCl end groups form by 2,1-insertion of VC into palladium hydride complexes, as revealed by detailed labeling studies. This first example of VC incorporation (up to 0.4 mol %) clearly shows that insertion (co)polymerization of VC is in principle feasible.

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