Tricyclo[4.3.1.0 1,6 ]deca‐2,4‐dienetricarbonyl‐chromium, a Homoaromatic Transition Metal Complex
1970; Wiley; Volume: 9; Issue: 4 Linguagem: Inglês
10.1002/anie.197003031
ISSN1521-3773
AutoresWolf‐Eckhard Bleck, Wolfram Grimme, Harald Günther, Emanuel Vogel,
Tópico(s)Asymmetric Hydrogenation and Catalysis
ResumoAngewandte Chemie International Edition in EnglishVolume 9, Issue 4 p. 303-304 Communication Tricyclo[4.3.1.01,6]deca-2,4-dienetricarbonyl-chromium, a Homoaromatic Transition Metal Complex Dr. Wolf-Eckhard Bleck, Dr. Wolf-Eckhard Bleck Institut für Organische Chemie der Universität, 5 Köln 1, Zülpicher Strasse 47 (Germany)Search for more papers by this authorPriv.-Doz. Dr. Wolfram Grimme, Priv.-Doz. Dr. Wolfram Grimme Institut für Organische Chemie der Universität, 5 Köln 1, Zülpicher Strasse 47 (Germany)Search for more papers by this authorPriv.-Doz. Dr. Harald Günther, Priv.-Doz. Dr. Harald Günther Institut für Organische Chemie der Universität, 5 Köln 1, Zülpicher Strasse 47 (Germany)Search for more papers by this authorProf. Dr. Emanuel Vogel, Corresponding Author Prof. Dr. Emanuel Vogel Institut für Organische Chemie der Universität, 5 Köln 1, Zülpicher Strasse 47 (Germany)Institut für Organische Chemie der Universität, 5 Köln 1, Zülpicher Strasse 47 (Germany)Search for more papers by this author Dr. Wolf-Eckhard Bleck, Dr. Wolf-Eckhard Bleck Institut für Organische Chemie der Universität, 5 Köln 1, Zülpicher Strasse 47 (Germany)Search for more papers by this authorPriv.-Doz. Dr. Wolfram Grimme, Priv.-Doz. Dr. Wolfram Grimme Institut für Organische Chemie der Universität, 5 Köln 1, Zülpicher Strasse 47 (Germany)Search for more papers by this authorPriv.-Doz. Dr. Harald Günther, Priv.-Doz. Dr. Harald Günther Institut für Organische Chemie der Universität, 5 Köln 1, Zülpicher Strasse 47 (Germany)Search for more papers by this authorProf. Dr. Emanuel Vogel, Corresponding Author Prof. Dr. Emanuel Vogel Institut für Organische Chemie der Universität, 5 Köln 1, Zülpicher Strasse 47 (Germany)Institut für Organische Chemie der Universität, 5 Köln 1, Zülpicher Strasse 47 (Germany)Search for more papers by this author First published: April 1970 https://doi.org/10.1002/anie.197003031Citations: 17AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat No abstract is available for this article. References 1 E. Vogel, W. Wiedemann, H. Kiefer, and W. F. Harrison, Tetrahedron Letters 1963, 673; E. Vogel, W. Wiedemann, H.-D. Roth, J. Eimer, and H. Günther, Liebigs Ann. Chem., in press. 2 Regarding the concept of homoaromaticity, see S. Winstein in Aromaticity. Special Publ. No. 21. The Chemical Society, London 1967, p. 5; Quart Rev. (chem. Soc. London) 23, 141 (1969). 3 H. Günther and H.-H. Hinrichs, Liebigs Ann. Chem. 706, 1 (1967). 4 W. Hieber, W. Abeck, and H. K. Platzer, Z. anorg. allg. Chem. 280, 252 (1955). 5 E. W. Abel, M. A. Bennett, and G. Wilkinson, J. chem. Soc. (London) 1959, 2323. 6 W.-E. Bleck, Dissertation, Universität Köln 1969. 7 H. Günther, Naturforschg. 20b, 948 (1965); H. Günther, R. Wenzl, and W. Grimme, J. Amer. chem. Soc. 91, 3808 (1969). 8 X-ray structure analysis of 1,6-methano-[10]annulene-2-carboxylic acid, see M. Dobler and J. D. Dunitz, Helv. chim. Acta 48, 1429 (1965). 9 X-ray structure analysis of 1,6-methano-[10]annulenetricarbonylchromium, see P. E. Baikie and O. S. Mills, J. chem. Soc. (London) A 1969, 328. 10 Compound (6) was prepared by reaction of (1) with dodecacarbonyltriiron in boiling benzene (6 h). 11 H. Günther and R. Wenzel, Angew. Chem. 81, 919 (1969); Angew. Chem. internat. Edit. 8, 900 (1969). In the table, the data for (6) and for benzocyclobutadienetricarbonyliron have been inadvertently interchanged; moreover τA,A' should read 5.10 instead of 5.51 ppm. 12 The spectrum corresponds to that of bicyclo[4.2.0]octa-2,4-dienetricarbonyliron. T. A. Manuel and F. G. A. Stone, J. Amer. chem. Soc. 82, 366 (1960). 13 R. L. Beddoes, P. F. Lindley, and O. S. Mills, Angew. Chem. 82, 293 (1970); Angew. Chem. internat. Edit. 9, 304 (1970). 14 C. J. Fritchie jr., Acta crystallogr. 20, 27 (1966). 15 A complex analogous to (2) was obtained on reaction of bicyclo[4.4.1]undeca-1,3,5-triene [1] with triamminetricarbonylchromium [6, 13]. Citing Literature Volume9, Issue4April 1970Pages 303-304 ReferencesRelatedInformation
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