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A Rhodium Peroxido Complex in Mono‐, Di‐, and Peroxygenation Reactions

2011; Wiley; Volume: 50; Issue: 14 Linguagem: Inglês

10.1002/anie.201007315

1521-3773

Gregor Meier, Thomas Braun,

Synthesis and Catalytic Reactions

A versatile peroxido complex: The rhodium peroxido complex 1, which can be prepared from 2 and dioxygen, participates in mono-oxygenation of a phosphine and dioxygenation of tetrakis(dimethylamino)ethylene to give, respectively, phosphine oxide and a urea derivative, while peroxygenation of 9,10-dimethylanthracene to yield the anthracene endoperoxide takes place in the presence of dioxygen and substoichiometric amounts of 1 (see scheme). Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.