Gold( i )-catalyzed formation of dihydroquinolines and indoles from N-aminophenyl propargyl malonates
2010; Royal Society of Chemistry; Volume: 47; Issue: 1 Linguagem: Inglês
10.1039/c0cc00033g
ISSN1364-548X
AutoresColombe Gronnier, Yann Odabachian, Fabien Gagosz,
Tópico(s)Catalytic Cross-Coupling Reactions
ResumoThe use of [XPhosAu(NCMe)]SbF(6) in nitromethane at 100 °C allows the rapid and efficient formation of variously substituted dihydroquinolines, which can be subsequently converted into indoles by a rare photochemical rearrangement.
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