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Rhodium(I)‐Catalyzed Redox‐Economic Cross‐Coupling of Carboxylic Acids with Arenes Directed by N‐Containing Groups

2013; Wiley; Volume: 52; Issue: 7 Linguagem: Inglês

10.1002/anie.201208362

ISSN

1521-3773

Autores

Fei Pan, Zhi‐Quan Lei, Hui Wang, Hu Li, Jian Sun, Zhang‐Jie Shi,

Tópico(s)

Catalytic Alkyne Reactions

Resumo

Angewandte Chemie International EditionVolume 52, Issue 7 p. 2063-2067 Communication Rhodium(I)-Catalyzed Redox-Economic Cross-Coupling of Carboxylic Acids with Arenes Directed by N-Containing Groups† Fei Pan, Fei Pan Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Education College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871 (China) http://www.chem.pku.edu.cn/zshi/Search for more papers by this authorZhi-Quan Lei, Zhi-Quan Lei Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Education College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871 (China) http://www.chem.pku.edu.cn/zshi/ Chengdu Institute of Biology, Chinese Academy of Science, Chengdu, Sichuan 400062 (China) http://www.cib.cas.cn/jgsz/kyxt/sysmk/trcwzxtz/sjtz/Search for more papers by this authorHui Wang, Hui Wang Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Education College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871 (China) http://www.chem.pku.edu.cn/zshi/Search for more papers by this authorHu Li, Hu Li Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Education College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871 (China) http://www.chem.pku.edu.cn/zshi/Search for more papers by this authorProf. Dr. Jian Sun, Corresponding Author Prof. Dr. Jian Sun [email protected] Chengdu Institute of Biology, Chinese Academy of Science, Chengdu, Sichuan 400062 (China) http://www.cib.cas.cn/jgsz/kyxt/sysmk/trcwzxtz/sjtz/ Jian Sun, Chengdu Institute of Biology, Chinese Academy of Science, Chengdu, Sichuan 400062 (China) http://www.cib.cas.cn/jgsz/kyxt/sysmk/trcwzxtz/sjtz/ Zhang-Jie Shi, Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Education College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871 (China) http://www.chem.pku.edu.cn/zshi/Search for more papers by this authorProf. Dr. Zhang-Jie Shi, Corresponding Author Prof. Dr. Zhang-Jie Shi [email protected] Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Education College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871 (China) http://www.chem.pku.edu.cn/zshi/ State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai 200032 (China) Jian Sun, Chengdu Institute of Biology, Chinese Academy of Science, Chengdu, Sichuan 400062 (China) http://www.cib.cas.cn/jgsz/kyxt/sysmk/trcwzxtz/sjtz/ Zhang-Jie Shi, Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Education College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871 (China) http://www.chem.pku.edu.cn/zshi/Search for more papers by this author Fei Pan, Fei Pan Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Education College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871 (China) http://www.chem.pku.edu.cn/zshi/Search for more papers by this authorZhi-Quan Lei, Zhi-Quan Lei Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Education College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871 (China) http://www.chem.pku.edu.cn/zshi/ Chengdu Institute of Biology, Chinese Academy of Science, Chengdu, Sichuan 400062 (China) http://www.cib.cas.cn/jgsz/kyxt/sysmk/trcwzxtz/sjtz/Search for more papers by this authorHui Wang, Hui Wang Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Education College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871 (China) http://www.chem.pku.edu.cn/zshi/Search for more papers by this authorHu Li, Hu Li Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Education College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871 (China) http://www.chem.pku.edu.cn/zshi/Search for more papers by this authorProf. Dr. Jian Sun, Corresponding Author Prof. Dr. Jian Sun [email protected] Chengdu Institute of Biology, Chinese Academy of Science, Chengdu, Sichuan 400062 (China) http://www.cib.cas.cn/jgsz/kyxt/sysmk/trcwzxtz/sjtz/ Jian Sun, Chengdu Institute of Biology, Chinese Academy of Science, Chengdu, Sichuan 400062 (China) http://www.cib.cas.cn/jgsz/kyxt/sysmk/trcwzxtz/sjtz/ Zhang-Jie Shi, Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Education College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871 (China) http://www.chem.pku.edu.cn/zshi/Search for more papers by this authorProf. Dr. Zhang-Jie Shi, Corresponding Author Prof. Dr. Zhang-Jie Shi [email protected] Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Education College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871 (China) http://www.chem.pku.edu.cn/zshi/ State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai 200032 (China) Jian Sun, Chengdu Institute of Biology, Chinese Academy of Science, Chengdu, Sichuan 400062 (China) http://www.cib.cas.cn/jgsz/kyxt/sysmk/trcwzxtz/sjtz/ Zhang-Jie Shi, Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Education College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871 (China) http://www.chem.pku.edu.cn/zshi/Search for more papers by this author First published: 10 January 2013 https://doi.org/10.1002/anie.201208362Citations: 141 † Support of this work by the “973” Project from the MOST of China (2009CB825300) and NSFC (Nos. 20925207 and 21002001) is gratefully acknowledged. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Marked absent: The pseudo-oxidative decarboxylative coupling of carboxylic acids and arenes using rhodium(I) in the absence of an oxidant is described. The study offers a new convenient method for the construction of CC/C bonds. 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