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A Co 36 Cluster Assembled from the Reaction of Cobalt Pivalate with 2,3‐Dicarboxypyrazine

2009; Wiley; Volume: 48; Issue: 49 Linguagem: Inglês

10.1002/anie.200904743

1521-3773

Pablo Alborés, Eva Rentschler,

Nanocluster Synthesis and Applications

Angewandte Chemie International EditionVolume 48, Issue 49 p. 9366-9370 Communication A Co36 Cluster Assembled from the Reaction of Cobalt Pivalate with 2,3-Dicarboxypyrazine† Pablo Alborés Dr., Pablo Alborés Dr. [email protected] [email protected] Departamento de Química Inorgánica, Analítica y Química Física-INQUIMAE (CONICET), Universidad de Buenos Aires (Argentina) Institut für Anorganische und Analytische Chemie, Johannes-Gutenberg-Universität, 55099 Mainz (Germany)Search for more papers by this authorEva Rentschler Prof. Dr., Eva Rentschler Prof. Dr. Institut für Anorganische und Analytische Chemie, Johannes-Gutenberg-Universität, 55099 Mainz (Germany)Search for more papers by this author Pablo Alborés Dr., Pablo Alborés Dr. [email protected] [email protected] Departamento de Química Inorgánica, Analítica y Química Física-INQUIMAE (CONICET), Universidad de Buenos Aires (Argentina) Institut für Anorganische und Analytische Chemie, Johannes-Gutenberg-Universität, 55099 Mainz (Germany)Search for more papers by this authorEva Rentschler Prof. Dr., Eva Rentschler Prof. Dr. Institut für Anorganische und Analytische Chemie, Johannes-Gutenberg-Universität, 55099 Mainz (Germany)Search for more papers by this author First published: 17 November 2009 https://doi.org/10.1002/anie.200904743Citations: 116 † We gratefully acknowledge the Alexander von Humboldt Foundation for granting a Post-Doctoral fellowship for P.A. P.A. is a member of the research staff of CONICET. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract A record Co36 cluster is prepared. This mixed-valent compound containing CoII and CoIII centers is formed in the reaction of a dinuclear cobalt pivalate species with the polydentate 2,3-dicarboxypyrazine ligand. In terms of magnetic properties it behaves as a {Co16–Co16} supramolecular dimer in which the S=4 spin ground states of each monomer do not interact. Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_200904743_sm_miscellaneous_information.pdf593.7 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1A. J. Tasiopoulos, A. Vinslava, W. Wernsdorfer, K. A. Abboud, G. Christou, Angew. Chem. 2004, 116, 2169–2173; Angew. Chem. Int. Ed. 2004, 43, 2117–2121. 2G. Christou, D. Gatteschi, D. N. Hendrickson, R. Sessoli, MRS Bull. 2000, 25, 66–71; D. Gatteschi, R. Sessoli, Angew. Chem. 2003, 115, 278–309; Angew. Chem. Int. Ed. 2003, 42, 268–297. 3L. Thomas, F. Lionti, R. Ballou, D. Gatteschi, R. Sessoli, B. 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