Nickel-catalyzed carbometallation of functionalized silylalkynes by grignard reagents
1979; Elsevier BV; Volume: 20; Issue: 19 Linguagem: Inglês
10.1016/s0040-4039(01)93622-6
ISSN1873-3581
AutoresBarry B. Snider, Robin S. E. Conn, Michael Karras,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoSyntheses of vinylsilanes by the nickel catalyzed addition of methyl-magnesium bromide to functionalized silylalkynes are described. Simple syntheses of geraniol and farnesol are reported.
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