The difference in strength of BF3-complexes of aromatic and aliphatic aldehydes
1991; Elsevier BV; Volume: 32; Issue: 25 Linguagem: Inglês
10.1016/0040-4039(91)80634-i
ISSN1873-3581
Autores Tópico(s)Crystallography and molecular interactions
Resumoab initio MO computations have shown that the difference in energy between syn and anti complexation is much larger for benzaldehyde/BF3 than for acetaldehyde/BF3. The BO bond strength is much greater for the anti PhCHO·BF3 than for its syn isomer and for all the CH3CHO·BF3 complexes.
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