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Strong Ultra‐Broadband Near‐Infrared Photoluminescence from Bismuth‐Embedded Zeolites and Their Derivatives

2009; Volume: 21; Issue: 36 Linguagem: Inglês

10.1002/adma.200900573

1521-4095

Hong‐Tao Sun, Akinobu Hosokawa, Yuji Miwa, Fumiaki Shimaoka, Minoru Fujii, Minoru Mizuhata, Shinji Hayashi, Shigehito Deki,

Glass properties and applications

Advanced MaterialsVolume 21, Issue 36 p. 3694-3698 Communication Strong Ultra-Broadband Near-Infrared Photoluminescence from Bismuth-Embedded Zeolites and Their Derivatives Hong-Tao Sun, Corresponding Author Hong-Tao Sun Department of Electrical and Electronic Engineering Kobe University Kobe 657-8501 (Japan)Department of Electrical and Electronic Engineering Kobe University Kobe 657-8501 (Japan).Search for more papers by this authorAkinobu Hosokawa, Akinobu Hosokawa Department of Chemical Science and Engineering Kobe University Kobe 657-8501 (Japan)Search for more papers by this authorYuji Miwa, Yuji Miwa Department of Electrical and Electronic Engineering Kobe University Kobe 657-8501 (Japan)Search for more papers by this authorFumiaki Shimaoka, Fumiaki Shimaoka Department of Electrical and Electronic Engineering Kobe University Kobe 657-8501 (Japan)Search for more papers by this authorMinoru Fujii, Corresponding Author Minoru Fujii Department of Electrical and Electronic Engineering Kobe University Kobe 657-8501 (Japan)Department of Electrical and Electronic Engineering Kobe University Kobe 657-8501 (Japan).Search for more papers by this authorMinoru Mizuhata, Minoru Mizuhata Department of Chemical Science and Engineering Kobe University Kobe 657-8501 (Japan)Search for more papers by this authorShinji Hayashi, Shinji Hayashi Department of Electrical and Electronic Engineering Kobe University Kobe 657-8501 (Japan)Search for more papers by this authorShigehito Deki, Shigehito Deki Department of Chemical Science and Engineering Kobe University Kobe 657-8501 (Japan)Search for more papers by this author Hong-Tao Sun, Corresponding Author Hong-Tao Sun Department of Electrical and Electronic Engineering Kobe University Kobe 657-8501 (Japan)Department of Electrical and Electronic Engineering Kobe University Kobe 657-8501 (Japan).Search for more papers by this authorAkinobu Hosokawa, Akinobu Hosokawa Department of Chemical Science and Engineering Kobe University Kobe 657-8501 (Japan)Search for more papers by this authorYuji Miwa, Yuji Miwa Department of Electrical and Electronic Engineering Kobe University Kobe 657-8501 (Japan)Search for more papers by this authorFumiaki Shimaoka, Fumiaki Shimaoka Department of Electrical and Electronic Engineering Kobe University Kobe 657-8501 (Japan)Search for more papers by this authorMinoru Fujii, Corresponding Author Minoru Fujii Department of Electrical and Electronic Engineering Kobe University Kobe 657-8501 (Japan)Department of Electrical and Electronic Engineering Kobe University Kobe 657-8501 (Japan).Search for more papers by this authorMinoru Mizuhata, Minoru Mizuhata Department of Chemical Science and Engineering Kobe University Kobe 657-8501 (Japan)Search for more papers by this authorShinji Hayashi, Shinji Hayashi Department of Electrical and Electronic Engineering Kobe University Kobe 657-8501 (Japan)Search for more papers by this authorShigehito Deki, Shigehito Deki Department of Chemical Science and Engineering Kobe University Kobe 657-8501 (Japan)Search for more papers by this author First published: 22 September 2009 https://doi.org/10.1002/adma.200900573Citations: 99AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Zeolites with embedded bismuth compounds display strong, air-stable, long-lived, ultrabroadband, and tunable near-infrared photoluminescence (see picture). Bismuth ions not only act as luminescence-active centers, but also as blocks for selectively closing the "in–out windows" of water molecules. Bismuth active centers can be sealed in a low-vibrational environment by bismuth agglomerates even when the sample still contains a large amount of water. References 1a S. C. Larsen, J. Phys. Chem. C 2007, 111, 18464. 1b L. Tosheva, V. P. Valtchev, Chem. Mater. 2005, 17, 2494. 1c X. Bu, P. Feng, G. D. Stucky, Science 1997, 278, 2080. 1d X. Lou, L. A. Archer, Z. Yang, Adv. Mater. 2008, 20, 1. 1e R. Morris, P. Wheatley, Angew. Chem. 2008, 120, 5044. Angew. Chem. Int. Ed. 2008, 47, 4966. 1f G. Calzaferri, S. Huber, H. Maas, C. Minkowski, Angew. Chem. 2003, 115, 3860. Angew. Chem. Int. Ed. 2003, 42, 3732. 2a U. Kynast, V. Weiler, Adv. 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Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description adma_200900573_sm_suppdata.pdf466.5 KB suppdata Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume21, Issue36September 25, 2009Pages 3694-3698 ReferencesRelatedInformation