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Stepwise Construction of a Re–Pd Heterodinuclear Core Inside the Cavity of p ‐ t Bu‐Calix[4]arene

2003; Wiley; Volume: 42; Issue: 31 Linguagem: Inglês

10.1002/anie.200351530

1521-3773

Kentarou Iwasa, Takuya Kochi, Youichi Ishii,

Organometallic Complex Synthesis and Catalysis

A Re–Pd heterometallic core has been constructed inside the cavity of a calixarene ligand. An unprecedented calix[4]arene–rhenium complex can incorporate a {Pd(η3-C3H5)+} fragment to afford the phenoxo-bridged heterodinuclear complex [ReO2{p-tBu-calix[4]arene-(O)4}Pd(η3-C3H5)] (see picture). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2003/z51530_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.