Synthesis and X-ray Structural Analysis of Hydrido(thiolato) Platinum(II) Complexes
2009; Oxford University Press; Volume: 38; Issue: 5 Linguagem: Inglês
10.1246/cl.2009.400
ISSN1348-0715
AutoresNorio Nakata, Suzuka Yamamoto, W. Hashima, Akihiko Ishii,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoAbstract The oxidative addition of [Pt(η2-nb)(PPh3)2] with a sterically hindered thiol, TripSH (4, Trip = 9-triptycyl) in toluene afforded cis-hydrido(thiolato) PtII complex [PtH(STrip)(PPh3)2] (5), as thermally and moisture-stable colorless crystals in 91% yield. Complex 5 was fully characterized by 1H, 13C{1H}, and 31P{1H} NMR and IR spectroscopies, and the molecular structure of 5 was determined by X-ray crystallography.
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