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Specific Photobiocatalytic Oxyfunctionalization Reactions

2011; Wiley; Volume: 50; Issue: 45 Linguagem: Inglês

10.1002/anie.201105308

1521-3773

Ekaterina Churakova, Martin Kluge, René Ullrich, Isabel W. C. E. Arends, Martin Hofrichter, Frank Hollmann,

Advanced Nanomaterials in Catalysis

Turn a light on: Enantiospecific hydroxylation of nonactivated CH bonds as well as epoxidations of CC bonds are reported using a novel peroxidase from Agrocybe aegerita (AaeAPO). AaeAPO represents a more active and more versatile alternative to the current gold standard, chloroperoxidase. H2O2 was produced in situ by photocatalytic reduction of O2 using simple flavin adenine mononucleotide (FMN) catalysts. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.