“Umpolung” von Bor im [B(CN) 4 ] − Anion durch Reduktion zum Dianion [B(CN) 3 ] 2−
2011; Wiley; Volume: 123; Issue: 50 Linguagem: Inglês
10.1002/ange.201105848
ISSN1521-3757
AutoresEduard Bernhardt, Vera Bernhardt‐Pitchougina, Helge Willner, Nikolai Ignatíev,
Tópico(s)Inorganic Chemistry and Materials
ResumoEin homoleptisches Cyanoborat mit nukleophilem Boratom: Das beispiellose Dianion in den Salzen M2[B(CN)3] (M=Li, Na, K), das nukleophiles Bor in der Oxidationsstufe +I enthält, wurde durch reduktive B-C-Bindungsspaltung im [B(CN)4]−-Anion erhalten (siehe Schema) und durch 11B- und 13C-NMR- und Schwingungsspektroskopie sowie durch Strukturanalyse charakterisiert. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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