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Highly Efficient Cu(OAc) 2 ‐Catalyzed Dimerization of Monofunctionalized Hydrofullerenes Leading to Single‐Bonded [60]Fullerene Dimers

2011; Wiley; Volume: 51; Issue: 3 Linguagem: Inglês

10.1002/anie.201107505

1521-3773

Shirong Lu, Tienan Jin, Eunsang Kwon, Ming Bao, Yoshinori Yamamoto,

Catalytic C–H Functionalization Methods

Dimers are a girl's best friend: The title reaction allows the formation of single-bonded fullerene dimers with extremely high chemical yield and high compatibility with various functional groups, which are highly soluble in organic solvents. The use of Cu(OAc)2 catalyst with dimethylformamide or acetonitrile as additives under air is the critical factor in achieving the highly efficient catalytic dimerization. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.