Artigo Revisado por pares

An [Fe II 3 O] 4+ Core Wrapped by Two [Fe II L 3 ] − Units

2006; Wiley; Volume: 118; Issue: 33 Linguagem: Inglês

10.1002/ange.200602067

ISSN

1521-3757

Autores

K. Yoneda, Keiichi Adachi, Kyonosuke Nishio, Mikio Yamasaki, Akira Fuyuhiro, Motomi Katada, Sumio Kaizaki, Satoshi Kawata,

Tópico(s)

Lanthanide and Transition Metal Complexes

Resumo

Angewandte ChemieVolume 118, Issue 33 p. 5585-5587 Zuschrift An [FeII3O]4+ Core Wrapped by Two [FeIIL3]− Units† Ko Yoneda, Ko Yoneda Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Fax: (+81) 6-6850-5473 http://www.chem.sci.osaka-u.ac.jp/lab/kaizaki/ http://www.chem.sci.osaka-u.ac.jp/%7ekawata/Search for more papers by this authorKeiichi Adachi Dr., Keiichi Adachi Dr. Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Fax: (+81) 6-6850-5473 http://www.chem.sci.osaka-u.ac.jp/lab/kaizaki/ http://www.chem.sci.osaka-u.ac.jp/%7ekawata/Search for more papers by this authorKyonosuke Nishio, Kyonosuke Nishio Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Fax: (+81) 6-6850-5473 http://www.chem.sci.osaka-u.ac.jp/lab/kaizaki/ http://www.chem.sci.osaka-u.ac.jp/%7ekawata/Search for more papers by this authorMikio Yamasaki Dr., Mikio Yamasaki Dr. Single Crystal Structural Analysis Group, Application Laboratories, Rigaku Corporation, Akishima, Tokyo 196-8666, JapanSearch for more papers by this authorAkira Fuyuhiro Dr., Akira Fuyuhiro Dr. Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Fax: (+81) 6-6850-5473 http://www.chem.sci.osaka-u.ac.jp/lab/kaizaki/ http://www.chem.sci.osaka-u.ac.jp/%7ekawata/Search for more papers by this authorMotomi Katada Prof. Dr., Motomi Katada Prof. Dr. Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Hachiouji, Tokyo 192-0397, JapanSearch for more papers by this authorSumio Kaizaki Prof. Dr., Sumio Kaizaki Prof. Dr. [email protected] Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Fax: (+81) 6-6850-5473 http://www.chem.sci.osaka-u.ac.jp/lab/kaizaki/ http://www.chem.sci.osaka-u.ac.jp/%7ekawata/Search for more papers by this authorSatoshi Kawata Prof. Dr., Satoshi Kawata Prof. Dr. [email protected] Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Fax: (+81) 6-6850-5473 http://www.chem.sci.osaka-u.ac.jp/lab/kaizaki/ http://www.chem.sci.osaka-u.ac.jp/%7ekawata/Search for more papers by this author Ko Yoneda, Ko Yoneda Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Fax: (+81) 6-6850-5473 http://www.chem.sci.osaka-u.ac.jp/lab/kaizaki/ http://www.chem.sci.osaka-u.ac.jp/%7ekawata/Search for more papers by this authorKeiichi Adachi Dr., Keiichi Adachi Dr. Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Fax: (+81) 6-6850-5473 http://www.chem.sci.osaka-u.ac.jp/lab/kaizaki/ http://www.chem.sci.osaka-u.ac.jp/%7ekawata/Search for more papers by this authorKyonosuke Nishio, Kyonosuke Nishio Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Fax: (+81) 6-6850-5473 http://www.chem.sci.osaka-u.ac.jp/lab/kaizaki/ http://www.chem.sci.osaka-u.ac.jp/%7ekawata/Search for more papers by this authorMikio Yamasaki Dr., Mikio Yamasaki Dr. Single Crystal Structural Analysis Group, Application Laboratories, Rigaku Corporation, Akishima, Tokyo 196-8666, JapanSearch for more papers by this authorAkira Fuyuhiro Dr., Akira Fuyuhiro Dr. Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Fax: (+81) 6-6850-5473 http://www.chem.sci.osaka-u.ac.jp/lab/kaizaki/ http://www.chem.sci.osaka-u.ac.jp/%7ekawata/Search for more papers by this authorMotomi Katada Prof. Dr., Motomi Katada Prof. Dr. Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Hachiouji, Tokyo 192-0397, JapanSearch for more papers by this authorSumio Kaizaki Prof. Dr., Sumio Kaizaki Prof. Dr. [email protected] Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Fax: (+81) 6-6850-5473 http://www.chem.sci.osaka-u.ac.jp/lab/kaizaki/ http://www.chem.sci.osaka-u.ac.jp/%7ekawata/Search for more papers by this authorSatoshi Kawata Prof. Dr., Satoshi Kawata Prof. Dr. [email protected] Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Fax: (+81) 6-6850-5473 http://www.chem.sci.osaka-u.ac.jp/lab/kaizaki/ http://www.chem.sci.osaka-u.ac.jp/%7ekawata/Search for more papers by this author First published: 11 August 2006 https://doi.org/10.1002/ange.200602067Citations: 14 † This research was supported by Grants-in-Aid for Scientific Research (Nos. 17350026 and 18550055) and by a Grant-in-Aid for Scientific Research on Priority Areas (No. 434) from the Ministry of Education, Culture, Sports, Science, and Technology of Japan. L−=3,5-bis(pyridin-2-yl)pyrazolate. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Ein [FeII3O]4+-Kern im Bonbonpapier: 3,5-Bis(pyridin-2-yl)pyrazolat (L−) und Eisen(II)-Ionen bilden durch homochirale Selbstorganisation einen bis(tripelhelicalen) Cluster (siehe Bild), in dem ein dreieckiger [FeII3O]4+-Kern (Fe orange und gelb, O rot) von zwei [FeIIL3]−-Einheiten (Fe violett, L− grau) umgeben ist. Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2006/z602067_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1 1aS. Kitagawa, R. Kitaura, S. Noro, Angew. Chem. 2004, 116, 2388; 10.1002/ange.200300610 Google ScholarAngew. Chem. Int. Ed. 2004, 43, 2334; 10.1002/anie.200300610 CASPubMedWeb of Science®Google Scholar 1bJ. L. C. Rowsell, O. M. Yaghi, Angew. Chem. 2005, 117, 4748; 10.1002/ange.200462786 Google ScholarAngew. Chem. Int. Ed. 2005, 44, 4670; 10.1002/anie.200462786 CASPubMedWeb of Science®Google Scholar 1cM. Ruben, J. Rojo, F. J. Romero-Salguero, L. H. Uppadine, J.-M. Lehn, Angew. Chem. 2004, 116, 3728; 10.1002/ange.200300636 Google ScholarAngew. Chem. Int. Ed. 2004, 43, 3644; 10.1002/anie.200300636 CASPubMedWeb of Science®Google Scholar 1dJ.-M. Lehn, Supramolecular Chemistry-Concepts and Perspectives, Wiley-VCH, Weinheim, 1995. 10.1002/3527607439 Google Scholar 2 2aM. Albrecht, Angew. Chem. 2005, 117, 6606; 10.1002/ange.200501472 Google ScholarAngew. Chem. Int. Ed. 2005, 44, 6448; 10.1002/anie.200501472 CASPubMedWeb of Science®Google Scholar 2bM. J. Hannon, L. J. Childs, Supramol. Chem. 2004, 16, 7; 10.1080/10610270310001632386 CASWeb of Science®Google Scholar 2cJ.-M. Lehn, A. Rigault, Angew. Chem. 1988, 100, 1121; 10.1002/ange.19881000824 CASGoogle ScholarAngew. Chem. Int. Ed. Engl. 1988, 27, 1095. 10.1002/anie.198810951 Web of Science®Google Scholar 3M. Albrecht, Chem. Rev. 2001, 101, 3457. 10.1021/cr0103672 CASPubMedWeb of Science®Google Scholar 4aF. E. Hahn, T. Kreickmann, T. Pape, Dalton Trans. 2006, 769; 10.1039/B514442F CASPubMedWeb of Science®Google Scholar 4bJ. Garric, J.-M. Léger, I. Huc, Angew. Chem. 2005, 117, 1990; 10.1002/ange.200462898 Google ScholarAngew. Chem. Int. Ed. 2005, 44, 1954; 10.1002/anie.200462898 CASPubMedWeb of Science®Google Scholar 4cR. Zong, R. Thummel, Inorg. Chem. 2005, 44, 5984; 10.1021/ic050712w CASPubMedWeb of Science®Google Scholar 4dF. E. Hahn, C. S. Isfort, T. Pape, Angew. Chem. 2004, 116, 4779; 10.1002/ange.200490124 Google ScholarAngew. Chem. Int. Ed. 2004, 43, 4807; 10.1002/anie.200460188 CASPubMedWeb of Science®Google Scholar 4eJ. Hamacek, S. Blanc, M. Elhabiri, E. Leize, A. V. Dorsselaer, C. Piguet, A.-M. Albrecht-Gary, J. Am. Chem. Soc. 2003, 125, 1541; 10.1021/ja028861q CASPubMedWeb of Science®Google Scholar 4fL. J. Childs, N. W. Alcock, M. J. Hannon, Angew. Chem. 2002, 114, 4418; 10.1002/1521-3757(20021115)114:22 3.0.CO;2-S Google ScholarAngew. Chem. Int. Ed. 2002, 41, 4244; 10.1002/1521-3773(20021115)41:22 3.0.CO;2-5 CASPubMedWeb of Science®Google Scholar 4gJ. Hamblin, A. Jackson, N. W. Alcock, M. J. Hannon, J. Chem. Soc. Dalton Trans. 2002, 1635; 10.1039/b110137b CASWeb of Science®Google Scholar 4hR. W. Saalfrank, S. Trummer, H. Krautscheid, V. Schünemann, A. X. Trautwein, S. Hien, C. Stadler, J. Daub, Angew. Chem. 1996, 108, 2350; 10.1002/ange.19961081909 Google ScholarAngew. Chem. Int. Ed. Engl. 1996, 35, 2206. 10.1002/anie.199622061 CASWeb of Science®Google Scholar 5 5aK. Zeckert, J. Hamacek, J.-M. Senegas, N. Dalla-Favera, S. Floquet, G. Bernardinelli, C. Piguet, Angew. Chem. 2005, 117, 8168; 10.1002/ange.200503040 Google ScholarAngew. Chem. Int. Ed. 2005, 44, 7954; 10.1002/anie.200503040 CASPubMedWeb of Science®Google Scholar 5bC. J. Matthews, S. T. Onions, G. Morata, L. J. Davis, S. L. Heath, D. J. Price, Angew. Chem. 2003, 115, 3274; 10.1002/ange.200351634 Google ScholarAngew. Chem. Int. Ed. 2003, 42, 3166. 10.1002/anie.200351634 CASPubMedWeb of Science®Google Scholar 6 6aM. Bera, G. Aromí, W. T. Wong, D. Ray, Chem. Commun. 2006, 671; 10.1039/b514126e CASPubMedWeb of Science®Google Scholar 6bM. R. Bermejo, A. M. González-Noya, R. M. Pedrido, M. J. Romero, M. Vázquez, Angew. Chem. 2005, 117, 4254; 10.1002/ange.200500840 Google ScholarAngew. Chem. Int. Ed. 2005, 44, 4182; 10.1002/anie.200500840 CASPubMedWeb of Science®Google Scholar 6cR. W. Saalfrank, N. Löw, S. Trummer, G. M. Sheldrick, M. Teichert, D. Stalke, Eur. J. Inorg. Chem. 1998, 559. 10.1002/(SICI)1099-0682(199805)1998:5 3.0.CO;2-M CASWeb of Science®Google Scholar 7 7aK. Tanaka, A. Tengeiji, T. Kato, N. Toyama, M. Shionoya, Science 2003, 299, 1212; 10.1126/science.1080587 CASPubMedWeb of Science®Google Scholar 7bM. Elhabiri, R. Scopelliti, J.-C. G. Bünzli, C. Piguet, J. Am. Chem. Soc. 1999, 121, 10747. 10.1021/ja991854q CASWeb of Science®Google Scholar 8 8aS. Herold, S. J. Lippard, Inorg. Chem. 1997, 36, 50; 10.1021/ic960783i CASWeb of Science®Google Scholar 8bE. Y. Tshuva, S. J. Lippard, Chem. Rev. 2004, 104, 987. 10.1021/cr020622y CASPubMedWeb of Science®Google Scholar 9An aqueous solution (2 mL) of FeCl2⋅4 H2O (3.7 mM) was transferred into a glass tube, and then a 1:1 methanol/water mixture (2 mL) of HL (4.5 mM), NaNCS (1.5 mM), and NaOH (4.5 mM) was added without mixing under an N2 stream. Dark orange crystals began to form at ambient temperature after 2 days. Yield 80 %. Elemental analysis (%) calcd for C80H74N26O11S2Fe5: C 50.05, H 3.94, N 18.97; found: C 49.04, H 3.70, N 19.14. MS (positive ESI; 1:3 CH3OH/H2O): m/z: 811 [{FeII(μ-L)3}2FeII3(μ-O)]2+. Google Scholar 10A. K. Boudalis, J.-M. Clemente-Juan, F. Dahan, J.-P. Tuchagues, Inorg. Chem. 2004, 43, 1574. 10.1021/ic0351904 CASPubMedWeb of Science®Google Scholar 11Crystal structure analysis for 1: The data collection was carried out on a Rigaku RAXIS-RAPID diffractometer with graphite-monochromated MoKα radiation. The structure was solved by direct methods (Rigaku CrystalStructure, Molecular Structure Corporation) and refined with full-matrix least-squares techniques (SHELXL97[15]). Crystal data: C80H74N26O11S2Fe5, T=93 K, dark orange, tetragonal, space group I, Z=1, a=16.897(2), c=29.980(5) Å, V=8559(2) Å3, ρcalcd=1.489 g cm−3, μ(MoKα)=9.51 cm−1, 50 290 reflections collected, 2θ<59.9°, 12 349 independent reflections (Rint=0.026), 610 parameters, all non-hydrogen atoms anisotropic, all hydrogen atoms in calculated positions, R1=0.0396 (for 11 207 F<4σ(F)), wR2=0.1243, Flack parameter=0.006(10), GOF=1.062. CCDC-604887 (1) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif. Google Scholar 12A. K. Boudalis, Y. Sanakis, F. Dahan, M. Hendrich, J.-P. Tuchagues, Inorg. Chem. 2006, 45, 443. 10.1021/ic051652x CASPubMedWeb of Science®Google Scholar 13J. B. Vincent, H.-R. Chang, K. Folting, J. C. Huffman, G. Christou, D. N. Hendrickson, J. Am. Chem. Soc. 1987, 109, 5703. 10.1021/ja00253a023 CASWeb of Science®Google Scholar 14 14aS. G. Sreerama, S. Pal, Inorg. Chem. 2002, 41, 4843; 10.1021/ic0202559 CASPubMedWeb of Science®Google Scholar 14bT. C. Stamatatos, D. Foguet-Albiol, C. C. Stoumpos, C. P. Raptopoulou, A. Terzis, W. Wernsdorfer, S. P. Periepes, G. Christou, J. Am. Chem. Soc. 2005, 127, 15380. 10.1021/ja0558138 CASPubMedWeb of Science®Google Scholar 15G. M. Sheldrick, SHELXL97, University of Göttingen, Germany, 1997. Google Scholar Citing Literature Volume118, Issue33August 18, 2006Pages 5585-5587 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. ReferencesRelatedInformation

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