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Nanohybridization of Polyoxometalate Clusters and Single‐Wall Carbon Nanotubes: Applications in Molecular Cluster Batteries

2011; Wiley; Volume: 50; Issue: 15 Linguagem: Inglês

10.1002/anie.201007264

1521-3773

Naoya Kawasaki, Heng Wang, Ryo Nakanishi, Shun Hamanaka, Ryo Kitaura, Hisanori Shinohara, Toshihiko Yokoyama, Hirofumi Yoshikawa, Kunio Awaga,

Conducting polymers and applications

Angewandte Chemie International EditionVolume 50, Issue 15 p. 3471-3474 Communication Nanohybridization of Polyoxometalate Clusters and Single-Wall Carbon Nanotubes: Applications in Molecular Cluster Batteries† Naoya Kawasaki, Naoya Kawasaki Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Search for more papers by this authorHeng Wang, Heng Wang Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Search for more papers by this authorRyo Nakanishi, Ryo Nakanishi Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Search for more papers by this authorShun Hamanaka, Shun Hamanaka Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Search for more papers by this authorDr. Ryo Kitaura, Dr. Ryo Kitaura Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Search for more papers by this authorProf. Hisanori Shinohara, Prof. Hisanori Shinohara Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Search for more papers by this authorProf. Toshihiko Yokoyama, Prof. Toshihiko Yokoyama Institute for Molecular Sciences, 444-8585 Okazaki (Japan)Search for more papers by this authorDr. Hirofumi Yoshikawa, Corresponding Author Dr. Hirofumi Yoshikawa [email protected] Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Search for more papers by this authorProf. Kunio Awaga, Corresponding Author Prof. Kunio Awaga [email protected] Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484 CREST, JST, Furo-cho, Chikusa, 464-8602 Nagoya (Japan)Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Search for more papers by this author Naoya Kawasaki, Naoya Kawasaki Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Search for more papers by this authorHeng Wang, Heng Wang Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Search for more papers by this authorRyo Nakanishi, Ryo Nakanishi Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Search for more papers by this authorShun Hamanaka, Shun Hamanaka Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Search for more papers by this authorDr. Ryo Kitaura, Dr. Ryo Kitaura Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Search for more papers by this authorProf. Hisanori Shinohara, Prof. Hisanori Shinohara Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Search for more papers by this authorProf. Toshihiko Yokoyama, Prof. Toshihiko Yokoyama Institute for Molecular Sciences, 444-8585 Okazaki (Japan)Search for more papers by this authorDr. Hirofumi Yoshikawa, Corresponding Author Dr. Hirofumi Yoshikawa [email protected] Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Search for more papers by this authorProf. Kunio Awaga, Corresponding Author Prof. Kunio Awaga [email protected] Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484 CREST, JST, Furo-cho, Chikusa, 464-8602 Nagoya (Japan)Department of Chemistry and Research Centre for Materials Science, Nagoya University, Furo-cho, Chikusa, 464-8602 Nagoya (Japan), Fax: (+81) 52-789-2484Search for more papers by this author First published: 08 March 2011 https://doi.org/10.1002/anie.201007264Citations: 197 † This work has been performed with the approval of PF PAC (Proposal Nos 2008G586, 2009G528, and 2010G557). The authors are grateful to the Ministry of Education, Culture, Sports, Science, and Technology (MEXT) of Japan for a Grant-in-Aid for Scientific Research. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Charging clusters: A hybrid of polyoxometalate (POM) molecules individually adsorbed onto the surfaces of single-wall carbon nanotubes (SWNTs) can be used as a cathode-active material in rechargeable lithium batteries. This POM/SWNT battery exhibited a very high capacity (>300 Ah kg−1) with a short charging/discharging time (<2 h). Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201007264_sm_miscellaneous_information.pdf486.5 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1 1aT. W. Ebbesen, H. J. Lezec, H. Hiura, J. W. Bennett, H. F. Ghaemi, T. Thio, Nature 1996, 382, 54–56; 1bS. J. Tans, M. H. Devoret, H. Dai, A. Thess, R. E. Smalley, L. J. Geerligs, C. Dekker, Nature 1997, 386, 474–477; 1cE. W. Wong, P. E. Sheehan, C. M. 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