Template and pH‐Mediated Synthesis of Tetrahedral Indium Complexes [Cs⊂{In 4 (L) 4 }] + and [In 4 (H N L) 4 ] 4+ : Breaking the Symmetry of N ‐Centered C 3 (L) 3− To Give Neutral [In 4 (L) 4 ]

Artigo Revisado por pares

Template and pH‐Mediated Synthesis of Tetrahedral Indium Complexes [Cs⊂{In 4 (L) 4 }] + and [In 4 (H N L) 4 ] 4+ : Breaking the Symmetry of N ‐Centered C 3 (L) 3− To Give Neutral [In 4 (L) 4 ]

2008; Wiley; Volume: 47; Issue: 46 Linguagem: Inglês

10.1002/anie.200804225

ISSN

1521-3773

Autores

Rolf W. Saalfrank, Harald Maid, Andreas Scheurer, Frank W. Heinemann, Ralph Puchta, Walter Bauer, Daniel Stern, Dietmar Stalke,

Tópico(s)

Metal-Organic Frameworks: Synthesis and Applications

Resumo

Angewandte Chemie International EditionVolume 47, Issue 46 p. 8941-8945 Communication Template and pH-Mediated Synthesis of Tetrahedral Indium Complexes [Cs⊂{In4(L)4}]+ and [In4(HNL)4]4+: Breaking the Symmetry of N-Centered C3 (L)3− To Give Neutral [In4(L)4]† Rolf W. Saalfrank Prof. Dr., Rolf W. Saalfrank Prof. Dr. saalfrank@chemie.uni-erlangen.de Department Chemie und Pharmazie, Anorganische Chemie, Universität Erlangen-Nürnberg, Egerlandstr. 1, 91058 Erlangen (Germany), Fax: (+49) 9131-85-27396 http://www.chemie.uni-erlangen.de/saalfrank/Search for more papers by this authorHarald Maid Dr., Harald Maid Dr. Department Chemie und Pharmazie, Anorganische Chemie, Universität Erlangen-Nürnberg, Egerlandstr. 1, 91058 Erlangen (Germany), Fax: (+49) 9131-85-27396 http://www.chemie.uni-erlangen.de/saalfrank/Search for more papers by this authorAndreas Scheurer Dr., Andreas Scheurer Dr. Department Chemie und Pharmazie, Anorganische Chemie, Universität Erlangen-Nürnberg, Egerlandstr. 1, 91058 Erlangen (Germany), Fax: (+49) 9131-85-27396 http://www.chemie.uni-erlangen.de/saalfrank/Search for more papers by this authorFrank W. Heinemann Dr., Frank W. Heinemann Dr. Department Chemie und Pharmazie, Anorganische Chemie, Universität Erlangen-Nürnberg, Egerlandstr. 1, 91058 Erlangen (Germany), Fax: (+49) 9131-85-27396 http://www.chemie.uni-erlangen.de/saalfrank/Search for more papers by this authorRalph Puchta Dr., Ralph Puchta Dr. Department Chemie und Pharmazie, Anorganische Chemie, Universität Erlangen-Nürnberg, Egerlandstr. 1, 91058 Erlangen (Germany), Fax: (+49) 9131-85-27396 http://www.chemie.uni-erlangen.de/saalfrank/Search for more papers by this authorWalter Bauer Prof. Dr., Walter Bauer Prof. Dr. Department Chemie und Pharmazie, Organische Chemie, Henkestr. 42, 91054 Erlangen (Germany)Search for more papers by this authorDaniel Stern, Daniel Stern Institut für Anorganische Chemie der Universität Göttingen, Tammannstr. 4, 37077 Göttingen (Germany)Search for more papers by this authorDietmar Stalke Prof. Dr., Dietmar Stalke Prof. Dr. Institut für Anorganische Chemie der Universität Göttingen, Tammannstr. 4, 37077 Göttingen (Germany)Search for more papers by this author Rolf W. Saalfrank Prof. Dr., Rolf W. Saalfrank Prof. Dr. saalfrank@chemie.uni-erlangen.de Department Chemie und Pharmazie, Anorganische Chemie, Universität Erlangen-Nürnberg, Egerlandstr. 1, 91058 Erlangen (Germany), Fax: (+49) 9131-85-27396 http://www.chemie.uni-erlangen.de/saalfrank/Search for more papers by this authorHarald Maid Dr., Harald Maid Dr. Department Chemie und Pharmazie, Anorganische Chemie, Universität Erlangen-Nürnberg, Egerlandstr. 1, 91058 Erlangen (Germany), Fax: (+49) 9131-85-27396 http://www.chemie.uni-erlangen.de/saalfrank/Search for more papers by this authorAndreas Scheurer Dr., Andreas Scheurer Dr. Department Chemie und Pharmazie, Anorganische Chemie, Universität Erlangen-Nürnberg, Egerlandstr. 1, 91058 Erlangen (Germany), Fax: (+49) 9131-85-27396 http://www.chemie.uni-erlangen.de/saalfrank/Search for more papers by this authorFrank W. Heinemann Dr., Frank W. Heinemann Dr. Department Chemie und Pharmazie, Anorganische Chemie, Universität Erlangen-Nürnberg, Egerlandstr. 1, 91058 Erlangen (Germany), Fax: (+49) 9131-85-27396 http://www.chemie.uni-erlangen.de/saalfrank/Search for more papers by this authorRalph Puchta Dr., Ralph Puchta Dr. Department Chemie und Pharmazie, Anorganische Chemie, Universität Erlangen-Nürnberg, Egerlandstr. 1, 91058 Erlangen (Germany), Fax: (+49) 9131-85-27396 http://www.chemie.uni-erlangen.de/saalfrank/Search for more papers by this authorWalter Bauer Prof. Dr., Walter Bauer Prof. Dr. Department Chemie und Pharmazie, Organische Chemie, Henkestr. 42, 91054 Erlangen (Germany)Search for more papers by this authorDaniel Stern, Daniel Stern Institut für Anorganische Chemie der Universität Göttingen, Tammannstr. 4, 37077 Göttingen (Germany)Search for more papers by this authorDietmar Stalke Prof. Dr., Dietmar Stalke Prof. Dr. Institut für Anorganische Chemie der Universität Göttingen, Tammannstr. 4, 37077 Göttingen (Germany)Search for more papers by this author First published: 29 October 2008 https://doi.org/10.1002/anie.200804225Citations: 47 † Chelate Complexes, Part 39. This work was supported by the Deutsche Forschungsgemeinschaft SPP 1137 "Molecular Magnetism" (SA 276/26-1–3), SA 276/29-1, SFB 583, GK 312, SPP 1178 "Experimental Charge Density" (STA 334/14-1 and 2), the Bayerisches Langzeitprogrammm Neue Werkstoffe, and the Fonds der Chemischen Industrie. The generous allocation of premises by Prof. Dr. K. Meyer at the Institut für Anorganische Chemie (Universität Erlangen-Nürnberg) is gratefully acknowledged. We also thank Dr. M. Engeser, Kekulé-Institut für Organische Chemie und Biochemie, Rheinische Friedrich-Wilhelms-Universität, Bonn, for recording ESI spectra. Bruker AXS, Karlsruhe, and INCOATEC, Geesthacht, is acknowledged for continuous support. Part 38: Ref. [9a]. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Molecular Kinder eggs are generated from N-centered tripodal heptadentate tris(1,3-diketonate) ions (L3−) in the presence of indium ions. The tetrahedral complexes host a cesium ion ([Cs⊂{In4(L)4}]+, see picture) or four protons. Deprotonation of the species [In4(HNL)4]4+ generates the empty cage compound [In4(L)4], which comes with a break of the symmetry in the initial C3-symmetric tripodal ligand. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_200804225_sm_miscellaneous_information.pdf55.9 KB miscellaneous information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume47, Issue46November 3, 2008Pages 8941-8945 RelatedInformation

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Template and pH‐Mediated Synthesis of Tetrahedral Indium Complexes [Cs⊂{In 4 (L) 4 }] + and [In 4 (H N L) 4 ] 4+ : Breaking the Symmetry of N ‐Centered C 3 (L) 3− To Give Neutral [In 4 (L) 4 ]