Portal de Periódicos da CAPES

An Ultrafine, Water-Based Condensation Particle Counter and its Evaluation under Field Conditions

2008; Taylor & Francis; Volume: 42; Issue: 10 Linguagem: Inglês

10.1080/02786820802339579

1521-7388

Kenjiro Iida, Mark R. Stolzenburg, Peter H. McMurry, James N. Smith, F.R. Quant, Derek R. Oberreit, Patricia B. Keady, Arantza Eiguren-Fernández, Gregory S. Lewis, Nathan M. Kreisberg, Susanne V. Hering,

Atmospheric chemistry and aerosols

An ultrafine, water-based condensation particle counter (U-WCPC, TSI Model 3786) has been compared to a butanol-based ultrafine counter (U-BCPC, TSI Model 3025) for measurement of atmospheric and freeway-tunnel aerosols. The U-WCPC utilizes a warm, wet-walled growth tube to activate and grow particles through water condensation in a laminar-flow. It has an aerosol sampling rate of 0.3 L/min, and a nominal detection limit near 3 nm. Several field comparisons were made to the butanol-based instrument with the same nominal detection limit. For measurements of size-selected aerosols with diameters of 5 nm and larger the two instruments generally agreed, with a mean response within 5%. At 3 nm particle size differences were observed, and these differences varied with the data set. Measurements of ambient aerosol in Boulder, Colorado showed higher counting efficiency at 3 nm with the U-BCPC, while in a California freeway tunnel the opposite trend was observed, with higher counting efficiencies at 3 nm observed by the U-WCPC. For direct measurement of atmospheric aerosols, the two types of instruments yielded equivalent concentrations, independent of particle number concentration.