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A Camouflaged Icosahedral Carborane: Dodecamethyl‐1,12‐dicarba‐ closo ‐dodecaborane(12) and Related Compounds

1995; Wiley; Volume: 34; Issue: 12 Linguagem: Inglês

10.1002/anie.199513321

1521-3773

Wei Jiang, Carolyn B. Knobler, Mark D. Mortimer, M. Frederick Hawthorne,

Nuclear Physics and Applications

Angewandte Chemie International Edition in EnglishVolume 34, Issue 12 p. 1332-1334 Communication A Camouflaged Icosahedral Carborane: Dodecamethyl-1,12-dicarba-closo-dodecaborane(12) and Related Compounds† Wei Jiang, Wei Jiang Department of Chemistry and Biochemistry, University of California, Los Angeles, CA 90095 (USA), Telefax: Int. code +(310)825-5490Search for more papers by this authorDr. Carolyn B. Knobler, Dr. Carolyn B. Knobler Department of Chemistry and Biochemistry, University of California, Los Angeles, CA 90095 (USA), Telefax: Int. code +(310)825-5490Search for more papers by this authorDr. Mark D. Mortimer, Dr. Mark D. Mortimer Department of Chemistry and Biochemistry, University of California, Los Angeles, CA 90095 (USA), Telefax: Int. code +(310)825-5490Search for more papers by this authorProf. M. Frederick Hawthorne, Corresponding Author Prof. M. Frederick Hawthorne Department of Chemistry and Biochemistry, University of California, Los Angeles, CA 90095 (USA), Telefax: Int. code +(310)825-5490Department of Chemistry and Biochemistry, University of California, Los Angeles, CA 90095 (USA), Telefax: Int. code +(310)825-5490Search for more papers by this author Wei Jiang, Wei Jiang Department of Chemistry and Biochemistry, University of California, Los Angeles, CA 90095 (USA), Telefax: Int. code +(310)825-5490Search for more papers by this authorDr. Carolyn B. Knobler, Dr. Carolyn B. Knobler Department of Chemistry and Biochemistry, University of California, Los Angeles, CA 90095 (USA), Telefax: Int. code +(310)825-5490Search for more papers by this authorDr. Mark D. Mortimer, Dr. Mark D. Mortimer Department of Chemistry and Biochemistry, University of California, Los Angeles, CA 90095 (USA), Telefax: Int. code +(310)825-5490Search for more papers by this authorProf. M. Frederick Hawthorne, Corresponding Author Prof. M. Frederick Hawthorne Department of Chemistry and Biochemistry, University of California, Los Angeles, CA 90095 (USA), Telefax: Int. code +(310)825-5490Department of Chemistry and Biochemistry, University of California, Los Angeles, CA 90095 (USA), Telefax: Int. code +(310)825-5490Search for more papers by this author First published: July 7, 1995 https://doi.org/10.1002/anie.199513321Citations: 75 † This work was supported by the National Science Foundation (Grant CHE 9314037). AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Complete B-methylation is possible for 1,12-dicarba-closo-dodecaborane(12) derivatives that are substituted on one or both carbon atoms. Electrophilic substitution under harsh conditions affords rigid "hydrocarbon balls" in high yields. An example of these carboranes, the title compound (shown as a space-filling model on the right), has twelve methyl groups arranged in an icosahedral manner and supported on a carborane skeleton. Citing Literature Volume34, Issue12July 7, 1995Pages 1332-1334 RelatedInformation