Methyl transfer reaction from monomethyltin reagent under palladium(0) catalysis: a versatile method for labelling with carbon-11
2005; Royal Society of Chemistry; Issue: 1 Linguagem: Inglês
10.1039/b510286c
ISSN1364-548X
AutoresMickaël Huiban, Aline Huet, Louisa Barré, Franck Sobrio, Éric Fouquet, Cécile Perrio,
Tópico(s)Chemical Reactions and Isotopes
ResumoThe 11C-monomethylstannate prepared from [11C]-methyl iodide and Lappert's stannylene, was subject to a palladium-mediated cross-coupling reaction with an aryl halide under ligand-free conditions, to afford easily purified 11C-methyl(hetero)arenes in high radiochemical yields.
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