Single‐Molecule Magnetism in a Single‐Ion Triamidoamine Uranium(V) Terminal Mono‐Oxo Complex
2013; Wiley; Volume: 52; Issue: 18 Linguagem: Inglês
10.1002/anie.201301007
ISSN1521-3773
AutoresDavid M. King, Floriana Tuna, Jonathan McMaster, William Lewis, Alexander J. Blake, Eric J. L. McInnes, Stephen T. Liddle,
Tópico(s)Porphyrin and Phthalocyanine Chemistry
ResumoAngewandte Chemie International EditionVolume 52, Issue 18 p. 4921-4924 Communication Single-Molecule Magnetism in a Single-Ion Triamidoamine Uranium(V) Terminal Mono-Oxo Complex† David M. King, David M. King School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK) These authors contributed equally to this work.Search for more papers by this authorDr. Floriana Tuna, Dr. Floriana Tuna School of Chemistry and Photon Science Institute, University of Manchester, Oxford Road, Manchester, M13 9PL (UK) These authors contributed equally to this work.Search for more papers by this authorDr. Jonathan McMaster, Dr. Jonathan McMaster School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)Search for more papers by this authorDr. William Lewis, Dr. William Lewis School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)Search for more papers by this authorProf. Alexander J. Blake, Prof. Alexander J. Blake School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)Search for more papers by this authorProf. Eric J. L. McInnes, Corresponding Author Prof. Eric J. L. McInnes eric.mcinnes@manchester.ac.uk School of Chemistry and Photon Science Institute, University of Manchester, Oxford Road, Manchester, M13 9PL (UK) Eric J. L. McInnes, School of Chemistry and Photon Science Institute, University of Manchester, Oxford Road, Manchester, M13 9PL (UK) Stephen T. Liddle, School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)Search for more papers by this authorDr. Stephen T. Liddle, Corresponding Author Dr. Stephen T. Liddle stephen.liddle@nottingham.ac.uk School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK) Eric J. L. McInnes, School of Chemistry and Photon Science Institute, University of Manchester, Oxford Road, Manchester, M13 9PL (UK) Stephen T. Liddle, School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)Search for more papers by this author David M. King, David M. King School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK) These authors contributed equally to this work.Search for more papers by this authorDr. Floriana Tuna, Dr. Floriana Tuna School of Chemistry and Photon Science Institute, University of Manchester, Oxford Road, Manchester, M13 9PL (UK) These authors contributed equally to this work.Search for more papers by this authorDr. Jonathan McMaster, Dr. Jonathan McMaster School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)Search for more papers by this authorDr. William Lewis, Dr. William Lewis School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)Search for more papers by this authorProf. Alexander J. Blake, Prof. Alexander J. Blake School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)Search for more papers by this authorProf. Eric J. L. McInnes, Corresponding Author Prof. Eric J. L. McInnes eric.mcinnes@manchester.ac.uk School of Chemistry and Photon Science Institute, University of Manchester, Oxford Road, Manchester, M13 9PL (UK) Eric J. L. McInnes, School of Chemistry and Photon Science Institute, University of Manchester, Oxford Road, Manchester, M13 9PL (UK) Stephen T. Liddle, School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)Search for more papers by this authorDr. Stephen T. Liddle, Corresponding Author Dr. Stephen T. Liddle stephen.liddle@nottingham.ac.uk School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK) Eric J. L. McInnes, School of Chemistry and Photon Science Institute, University of Manchester, Oxford Road, Manchester, M13 9PL (UK) Stephen T. Liddle, School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)Search for more papers by this author First published: 08 April 2013 https://doi.org/10.1002/anie.201301007Citations: 121 † We thank the Royal Society, the Engineering and Physical Sciences Research Council, the European Research Council, the University of Nottingham, the University of Manchester, and the UK National Nuclear Laboratory for generously supporting this work, and also the EPSRC UK National EPR Facility. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Single-molecule magnets: Straightforward oxidation of a triamidoamine uranium(III) complex with trimethyl-N-oxide affords a uranium(V) terminal mono-oxo complex which is the first clear-cut example of a uranium(V) single-molecule magnet (SMM). This monometallic complex unambiguously shows that a strongly axially ligated and thus anisotropic ligand field can be used to overcome the limited magnetic anisotropy of uranium(V). Citing Literature Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description anie_201301007_sm_miscellaneous_information.pdf382.7 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume52, Issue18April 26, 2013Pages 4921-4924 RelatedInformation
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