Binaphthyl‐Modified Quaternary Phosphonium Salts as Chiral Phase‐Transfer Catalysts: Asymmetric Amination of β‐Keto Esters
2008; Wiley; Volume: 120; Issue: 49 Linguagem: Inglês
10.1002/ange.200804140
ISSN1521-3757
AutoresRongjun He, Xi‐Sheng Wang, Takuya Hashimoto, Keiji Maruoka,
Tópico(s)Advanced Synthetic Organic Chemistry
ResumoAngewandte ChemieVolume 120, Issue 49 p. 9608-9610 Zuschrift Binaphthyl-Modified Quaternary Phosphonium Salts as Chiral Phase-Transfer Catalysts: Asymmetric Amination of β-Keto Esters† Rongjun He Dr., Rongjun He Dr. Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, 606-8502, (Japan), Fax: (+81) 75-753-4041Search for more papers by this authorXisheng Wang, Xisheng Wang Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, 606-8502, (Japan), Fax: (+81) 75-753-4041Search for more papers by this authorTakuya Hashimoto, Takuya Hashimoto Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, 606-8502, (Japan), Fax: (+81) 75-753-4041Search for more papers by this authorKeiji Maruoka Prof. Dr., Keiji Maruoka Prof. Dr. [email protected] Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, 606-8502, (Japan), Fax: (+81) 75-753-4041Search for more papers by this author Rongjun He Dr., Rongjun He Dr. Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, 606-8502, (Japan), Fax: (+81) 75-753-4041Search for more papers by this authorXisheng Wang, Xisheng Wang Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, 606-8502, (Japan), Fax: (+81) 75-753-4041Search for more papers by this authorTakuya Hashimoto, Takuya Hashimoto Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, 606-8502, (Japan), Fax: (+81) 75-753-4041Search for more papers by this authorKeiji Maruoka Prof. Dr., Keiji Maruoka Prof. Dr. [email protected] Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, 606-8502, (Japan), Fax: (+81) 75-753-4041Search for more papers by this author First published: 20 November 2008 https://doi.org/10.1002/ange.200804140Citations: 74 † This work was supported by a Grant-in-Aid for Scientific Research on Priority Areas "Advanced Molecular Transformation of Carbon Resources" from the Ministry of Education, Culture, Sports, Science and Technology (Japan). Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Ein verlässlicher Phosphonium-PTC: Ein chirales Tetraalkylphosphoniumsalz wurde als Phasentransferkatalysator (PTC) für die asymmetrische Aminierung von β-Ketoestern in hoher Ausbeute und mit hohem ee-Wert eingesetzt (siehe Schema). Die asymmetrische Aminierung eines cyclischen fünfgliedrigen β-Ketoesters ist nützlich zur Herstellung eines Schlüsselintermediats bei der Synthese des Aldosereduktase-Inhibitors AS-3201 (Ranirestat). 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