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1, n ‐Hydrogen‐Atom Transfer (HAT) Reactions in Which n ≠5: An Updated Inventory

2014; Wiley; Volume: 20; Issue: 49 Linguagem: Inglês

10.1002/chem.201403951

ISSN

1521-3765

Autores

Malek Nechab, Shovan Mondal, Michèle P. Bertrand,

Tópico(s)

Oxidative Organic Chemistry Reactions

Resumo

Hydrogen-atom transfer (HAT) counts amongst the most widely investigated routes to carbon-centered radicals. Intramolecular processes involving 1,5-HAT are widespread to promote regioselective radical "CH activation". The aim of this review is to draw up a comprehensive inventory of the less commonly encountered 1,n-radical translocations (n≠5) with the aim to update this topic with the most recent relevant data.

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