Complexation and Fluorescence of Tricyclic Basic Dyes Encapsulated in Cucurbiturils
2008; Wiley; Volume: 9; Issue: 5 Linguagem: Inglês
10.1002/cphc.200700735
ISSN1439-7641
AutoresPedro Montes‐Navajas, Avelino Corma, Hermenegildo Garcı́a,
Tópico(s)Luminescence and Fluorescent Materials
ResumoAbstract Tricyclic basic dyes (proflavine, acridine orange, pyronine, pyronine Y, oxonine, thionine and methylene blue) often form one‐to‐one or two‐to‐one complexes with CB[7] and CB[8], respectively. In the case of pyronine Y, the complexes with CB[7] and CB[8] have a one‐to‐one and three‐to‐one stoichiometry, respectively. The binding constants for CB[7] complexes range from 3.07×10 6 to 1.70×10 7 m −1 . In the case of CB[8], the association constant varies between 3.24×10 13 and 2.50×10 16 m −2 . Overall, these binding constants are four orders of magnitude higher than those reported for the same dyes in β and γ ‐cyclodextrins. Formation of the host–guest complexes leads to an increase in the fluorescence quantum yields in the case of CB[7], while the dimeric or trimeric dye encapsulated in CB[8] are remarkably less fluorescent than the same dye in diluted solutions.
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