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BIBTEX RIS

Carbon‐Catalyzed Oxidative Dehydrogenation of n ‐Butane: Selective Site Formation during sp 3 ‐to‐sp 2 Lattice Rearrangement

2011; Wiley; Volume: 50; Issue: 14 Linguagem: Inglês

10.1002/anie.201006717

ISSN

1521-3773

Autores

Xi Liu, Benjamin Frank, Wei Zhang, Thomas Cotter, Robert Schlögl, Dang Sheng Su,

Tópico(s)

Advanced Photocatalysis Techniques

Resumo

Onions are a girl's best friend: While catalyzing the oxidative dehydrogenation of n-butane, the ultradispersed nanodiamond (UDD) transforms to onion-like carbon (OLC).This surface-activated bulk transformation from sp 3 to sp 2 -hybridized carbon goes in with an enhanced product selectivity to the desired butenes.In addition, the synthesis of OLC is achieved at 600 K lower temperature than reported so far..

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