Supramolecular Helix‐to‐Helix Induction: A 3D Anionic Framework Containing Double‐Helical Strands Templated by Cationic Triple‐Stranded Cluster Helicates
2008; Wiley; Volume: 47; Issue: 9 Linguagem: Inglês
10.1002/anie.200704874
ISSN1521-3773
AutoresJin‐Zhang Hou, Mian Li, Zhen Li, Shun‐Ze Zhan, Xiao‐Chun Huang, Dan Li,
Tópico(s)Supramolecular Chemistry and Complexes
ResumoAngewandte Chemie International EditionVolume 47, Issue 9 p. 1711-1714 Communication Supramolecular Helix-to-Helix Induction: A 3D Anionic Framework Containing Double-Helical Strands Templated by Cationic Triple-Stranded Cluster Helicates† Jin-Zhang Hou, Jin-Zhang Hou Department of Chemistry, Shantou University, Guangdong 515063, China, Fax: (+86) 754-290-2767Search for more papers by this authorMian Li, Mian Li Department of Chemistry, Shantou University, Guangdong 515063, China, Fax: (+86) 754-290-2767Search for more papers by this authorZhen Li, Zhen Li Department of Chemistry, Shantou University, Guangdong 515063, China, Fax: (+86) 754-290-2767Search for more papers by this authorShun-Ze Zhan, Shun-Ze Zhan Department of Chemistry, Shantou University, Guangdong 515063, China, Fax: (+86) 754-290-2767Search for more papers by this authorXiao-Chun Huang Dr., Xiao-Chun Huang Dr. Department of Chemistry, Shantou University, Guangdong 515063, China, Fax: (+86) 754-290-2767Search for more papers by this authorDan Li Prof. Dr., Dan Li Prof. Dr. [email protected] Department of Chemistry, Shantou University, Guangdong 515063, China, Fax: (+86) 754-290-2767Search for more papers by this author Jin-Zhang Hou, Jin-Zhang Hou Department of Chemistry, Shantou University, Guangdong 515063, China, Fax: (+86) 754-290-2767Search for more papers by this authorMian Li, Mian Li Department of Chemistry, Shantou University, Guangdong 515063, China, Fax: (+86) 754-290-2767Search for more papers by this authorZhen Li, Zhen Li Department of Chemistry, Shantou University, Guangdong 515063, China, Fax: (+86) 754-290-2767Search for more papers by this authorShun-Ze Zhan, Shun-Ze Zhan Department of Chemistry, Shantou University, Guangdong 515063, China, Fax: (+86) 754-290-2767Search for more papers by this authorXiao-Chun Huang Dr., Xiao-Chun Huang Dr. Department of Chemistry, Shantou University, Guangdong 515063, China, Fax: (+86) 754-290-2767Search for more papers by this authorDan Li Prof. Dr., Dan Li Prof. Dr. [email protected] Department of Chemistry, Shantou University, Guangdong 515063, China, Fax: (+86) 754-290-2767Search for more papers by this author First published: 11 February 2008 https://doi.org/10.1002/anie.200704874Citations: 75 † This work was financially supported by the National Natural Science Foundation of China (Grant Nos. 20571050 and 20771072). Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract All wrapped up: Supramolecular polymeric helices were fabricated by using cluster helicates as templates. The helicity of the template (see picture; gold spheres: Ni or Zn; blue spheres: O), upon hydrothermal treatment with CuSCN (gray spheres), is transferred to the strands of the resulting copper-based coordination polymer, which is wrapped around the helicate units in the final product. References 1aJ. D. Watson, F. H. C. Crick, Nature 1953, 171, 737; 1bJ.-M. Lehn, A. Rigault, J. Siegel, J. 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Chem. 2006, 45, 9163. 10Crystal data for 1 a: C81H67N27Ni5O7S3, tetragonal, space group I, Mr=1920.35, a=16.9518, b=16.9518, c=30.4260 Å, V=8743.363 Å3, Z=4, ρcalcd=1.459 g cm−3, μ=1.198 mm−1, T=173(2) K; R1=0.0681, wR2=0.1470. Crystal data for 2 a: C93H55N39O1S4Ni5Cu12, monoclinic, space group C2/c, Mr=2919.03, a=22.8664 (9), b=23.3568(10), c=19.6974(8) Å, β=95.2840(10)°, V=10 475.4(7) Å3, Z=4, ρcalcd=1.851 g cm−3, μ=3.400 mm−1, T=173(2) K; R1=0.0755, wR2=0.1384. Crystal data for 2 b: C93H55N39O1S4Zn5Cu12, monoclinic, space group C2/c, Mr=2952.33, a=22.8420(9), b=23.4045(9), c=19.8531(8) Å, β=95.9120(10)°, V=10 557.1(7) Å3, Z=4, ρcalcd=1.857 g cm−3, μ=3.618 mm−1, T=173(2) K; R1=0.0688, wR2=0.1383. Crystal data for 1 b is not shown because of the disorder of the anion and solvent molecules and the quality of the data. Since 1 a and 1 b are isostructural, we carried out the data refinement of 1 b using Squeeze in Platon, which gave the main framework of 1 b. The molecular formula of 1 b is ascertained from elemental analysis, thermogravimetric analysis, and IR spectroscopy, and is suggested to be C81H67N27Zn5O7S3, Mr=1953.80. Data collection was performed on a Bruker Smart Apex CCD diffractometer (MoKα radiation, λ=0.71073 Å) by using frames of 0.3° oscillation (4.56≤2θ≤50°). The structure was solved by direct methods, and all non-hydrogen atoms were subjected to anisotropic refinement by full-matrix least-squares methods on F2 by using the SHELXTL program (G. M. Sheldrick, SHELXLT 6.10, Bruker Analytical Instrumentation, Madison, Wisconsin, USA, 2000). The TWIN instruction of SHELXTL was used for 2 a,b. The C and N atoms of the CN− ligands are indistinguishable, and they are assigned randomly as C or N atoms. The hydrogen atoms were located from difference maps and refined with isotropic temperature factors (see the Supporting Information for crystallographic details). CCDC-664496, 664497, 664498, and 664499 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif 11 11aA. D. Cutland-Van Noord, J. W. Kampf, V. L. Pecoraro, Angew. Chem. 2002, 114, 4861; Angew. Chem. Int. Ed. 2002, 41, 4667; 11bY. Wang, J. Yu, Z. Shi, R. Xu, Chem. Eur. J. 2003, 9, 5048; 11cT. Sanji, N. Kato, M. Kato, M. Tanaka, Angew. Chem. 2005, 117, 7467; Angew. Chem. Int. Ed. 2005, 44, 7301; 11dC. He, Y. Zhao, D. Guo, Z. Lin, C. Duan, Eur. J. Inorg. Chem. 2007, 3451, and references therein. 12aZ.-E. Lin, J. Zhang, J.-T. Zhao, S.-T. Zheng, C.-Y. Pan, G.-M. Wang, G.-Y. Yang, Angew. Chem. 2005, 117, 7041; Angew. Chem. Int. Ed. 2005, 44, 6881; 12bC.-F. Wang, J.-L. Zuo, B. M. Bartlett, Y. Song, J. R. Long, X.-Z. You, J. Am. Chem. Soc. 2006, 128, 7162. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z704874_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume47, Issue9February 15, 2008Pages 1711-1714 ReferencesRelatedInformation
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