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Depolymerization of Cellulose Using Solid Catalysts in Ionic Liquids

2008; Wiley; Volume: 47; Issue: 42 Linguagem: Inglês

10.1002/anie.200802879

1521-3773

Roberto Rinaldi, Regina Palkovits, Ferdi Schüth,

Lignin and Wood Chemistry

Angewandte Chemie International EditionVolume 47, Issue 42 p. 8047-8050 Communication Depolymerization of Cellulose Using Solid Catalysts in Ionic Liquids† Roberto Rinaldi Dr., Roberto Rinaldi Dr. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany), Fax: (+49) 208-306-2995 http://www.mpi-muelheim.mpg.de/kofo/Search for more papers by this authorRegina Palkovits Dr., Regina Palkovits Dr. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany), Fax: (+49) 208-306-2995 http://www.mpi-muelheim.mpg.de/kofo/Search for more papers by this authorFerdi Schüth Prof. Dr., Ferdi Schüth Prof. Dr. [email protected] Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany), Fax: (+49) 208-306-2995 http://www.mpi-muelheim.mpg.de/kofo/Search for more papers by this author Roberto Rinaldi Dr., Roberto Rinaldi Dr. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany), Fax: (+49) 208-306-2995 http://www.mpi-muelheim.mpg.de/kofo/Search for more papers by this authorRegina Palkovits Dr., Regina Palkovits Dr. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany), Fax: (+49) 208-306-2995 http://www.mpi-muelheim.mpg.de/kofo/Search for more papers by this authorFerdi Schüth Prof. Dr., Ferdi Schüth Prof. Dr. [email protected] Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany), Fax: (+49) 208-306-2995 http://www.mpi-muelheim.mpg.de/kofo/Search for more papers by this author First published: 29 September 2008 https://doi.org/10.1002/anie.200802879Citations: 480 † We acknowledge financial support from the Max-Planck-Society and from the Cluster of Excellence RWTH-Aachen "Tailor-Made Fuels from Biomass". Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Wood you believe it! Solid acids act as powerful catalysts for the hydrolysis of cellulose dissolved in an ionic liquid. Cellulose undergoes selective depolymerization, yielding cellulose oligomers (cellooligomers) without any substantial formation of side products. Even wood, a lignocellulosic material, is hydrolyzed using this methodology. Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z802879_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1Y. Román-Leshkov, C. J. Barrett, Z. Y. Liu, J. Dumesic, Nature 2007, 447, 982–985. 2G. W. Huber, J. N. Chheda, C. J. Barrett, J. A. Dumesic, Science 2005, 308, 1446–1450. 3A. Corma, S. Iborra, A. Velty, Chem. Rev. 2007, 107, 2411–2502. 4Y. Román-Leshkov, J. N. Chheda, J. A. Dumesic, Science 2006, 312, 1933–1937. 5J. Tollefson, Nature 2008, 451, 880–883. 6U.S. DOE. 2006. 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