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A Microporous Metal–Organic Framework for Gas‐Chromatographic Separation of Alkanes

2006; Wiley; Volume: 45; Issue: 9 Linguagem: Inglês

10.1002/anie.200502844

1521-3773

Banglin Chen, Chengdu Liang, Jun Yang, Damacio S. Contreras, Yvette L. Clancy, Emil B. Lobkovsky, Omar M. Yaghi, Sheng Dai,

Molecular Sensors and Ion Detection

Filling the pores: A zinc-based metal–organic framework (MOF) can be transformed reversibly from an open (a) to a dense (b) configuration. The microporous solid is the first example of a MOF that is highly selective in the gas-chromatographic separation of alkanes.