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A total synthesis of guanacastepene C

2005; Royal Society of Chemistry; Issue: 35 Linguagem: Inglês

10.1039/b506931a

1364-548X

Goverdhan Mehta, K. Pallavi, Jayant D. Umarye,

Cancer Treatment and Pharmacology

A total synthesis of the structure corresponding to the novel tricyclic diterpene guanacastepene C has been realized in which a Knoevenagel cyclization serves as a key step to annulate the six-membered C-ring on a stereochemically secured bicyclic hydroazulene precursor.