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A Metallacryptand‐Based Manganese(II)–Cobalt(II) Ferrimagnet with a Three‐Dimensional Honeycomb Open‐Framework Architecture
2008; Wiley; Volume: 47; Issue: 22 Linguagem: Inglês
10.1002/anie.200800208
ISSN1521-3773
AutoresEmilio Pardo, Danielle Cangussu, Marie‐Claire Dul, Rodrigue Lescouëzec, P. Herson, Yves Journaux, Emerson F. Pedroso, Cynthia L. M. Pereira, M. Carmen Muñoz, Rafael Ruiz‐García, Joan Cano, Pedro Amorós, Miguel Julve, Francesc Lloret,
Tópico(s)Advanced NMR Techniques and Applications
ResumoAngewandte Chemie International EditionVolume 47, Issue 22 p. 4211-4216 Communication A Metallacryptand-Based Manganese(II)–Cobalt(II) Ferrimagnet with a Three-Dimensional Honeycomb Open-Framework Architecture† Emilio Pardo Dr., Emilio Pardo Dr. Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Université Pierre et Marie Curie-Paris 6, UMR 7071, Paris 75252, France, Fax:(+33) 144-273-841Search for more papers by this authorDanielle Cangussu Dr., Danielle Cangussu Dr. Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Université Pierre et Marie Curie-Paris 6, UMR 7071, Paris 75252, France, Fax:(+33) 144-273-841Search for more papers by this authorMarie-Claire Dul, Marie-Claire Dul Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Université Pierre et Marie Curie-Paris 6, UMR 7071, Paris 75252, France, Fax:(+33) 144-273-841Search for more papers by this authorRodrigue Lescouëzec Dr., Rodrigue Lescouëzec Dr. Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Université Pierre et Marie Curie-Paris 6, UMR 7071, Paris 75252, France, Fax:(+33) 144-273-841Search for more papers by this authorPatrick Herson, Patrick Herson Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Université Pierre et Marie Curie-Paris 6, UMR 7071, Paris 75252, France, Fax:(+33) 144-273-841Search for more papers by this authorYves Journaux Dr., Yves Journaux Dr. [email protected] Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Université Pierre et Marie Curie-Paris 6, UMR 7071, Paris 75252, France, Fax:(+33) 144-273-841Search for more papers by this authorEmerson F. Pedroso Dr., Emerson F. Pedroso Dr. Departamento de Química, Centro Federal de Educação Tecnológica de Minas Gerais, Belo Horizonte-MG 30480-000, Minas Gerais, BrazilSearch for more papers by this authorCynthia L. M. Pereira Dr., Cynthia L. M. Pereira Dr. Departamento de Química, Universidade Federal de Juiz de Fora, Juiz de Fora 36036-330, Minas Gerais, BrazilSearch for more papers by this authorM. Carmen Muñoz Prof. Dr., M. Carmen Muñoz Prof. Dr. Departamento de Física Aplicada, Universidad Politécnica de València, València 46071, SpainSearch for more papers by this authorRafael Ruiz-García Dr., Rafael Ruiz-García Dr. Departament de Química Orgànica, Instituto de Ciencia Molecular (ICMOL), and Fundació General de la Universitat de València (FGUV), Universitat de València, Paterna 46980, València, SpainSearch for more papers by this authorJoan Cano Dr., Joan Cano Dr. Departament de Química Inorgànica, Institut de Química Teòrica i Computacional (IQTC) and Institut de Nanociència i Nanotecnologia (IN2UB), and Institució Catalana de Recerca i Estudis Avançats (ICREA), Universitat de Barcelona, Barcelona 08028, SpainSearch for more papers by this authorPedro Amorós Prof. Dr., Pedro Amorós Prof. Dr. Institut de Ciència dels Materials (ICMUV), Universitat de València, Paterna 46980, València, SpainSearch for more papers by this authorMiguel Julve Prof. Dr., Miguel Julve Prof. Dr. Departament de Química Inorgànica, Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna 46980, València, Spain, Fax: (+34) 963-544-859Search for more papers by this authorFrancesc Lloret Prof. Dr., Francesc Lloret Prof. Dr. [email protected] Departament de Química Inorgànica, Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna 46980, València, Spain, Fax: (+34) 963-544-859Search for more papers by this author Emilio Pardo Dr., Emilio Pardo Dr. Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Université Pierre et Marie Curie-Paris 6, UMR 7071, Paris 75252, France, Fax:(+33) 144-273-841Search for more papers by this authorDanielle Cangussu Dr., Danielle Cangussu Dr. Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Université Pierre et Marie Curie-Paris 6, UMR 7071, Paris 75252, France, Fax:(+33) 144-273-841Search for more papers by this authorMarie-Claire Dul, Marie-Claire Dul Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Université Pierre et Marie Curie-Paris 6, UMR 7071, Paris 75252, France, Fax:(+33) 144-273-841Search for more papers by this authorRodrigue Lescouëzec Dr., Rodrigue Lescouëzec Dr. Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Université Pierre et Marie Curie-Paris 6, UMR 7071, Paris 75252, France, Fax:(+33) 144-273-841Search for more papers by this authorPatrick Herson, Patrick Herson Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Université Pierre et Marie Curie-Paris 6, UMR 7071, Paris 75252, France, Fax:(+33) 144-273-841Search for more papers by this authorYves Journaux Dr., Yves Journaux Dr. [email protected] Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Université Pierre et Marie Curie-Paris 6, UMR 7071, Paris 75252, France, Fax:(+33) 144-273-841Search for more papers by this authorEmerson F. Pedroso Dr., Emerson F. Pedroso Dr. Departamento de Química, Centro Federal de Educação Tecnológica de Minas Gerais, Belo Horizonte-MG 30480-000, Minas Gerais, BrazilSearch for more papers by this authorCynthia L. M. Pereira Dr., Cynthia L. M. Pereira Dr. Departamento de Química, Universidade Federal de Juiz de Fora, Juiz de Fora 36036-330, Minas Gerais, BrazilSearch for more papers by this authorM. Carmen Muñoz Prof. Dr., M. Carmen Muñoz Prof. Dr. Departamento de Física Aplicada, Universidad Politécnica de València, València 46071, SpainSearch for more papers by this authorRafael Ruiz-García Dr., Rafael Ruiz-García Dr. Departament de Química Orgànica, Instituto de Ciencia Molecular (ICMOL), and Fundació General de la Universitat de València (FGUV), Universitat de València, Paterna 46980, València, SpainSearch for more papers by this authorJoan Cano Dr., Joan Cano Dr. Departament de Química Inorgànica, Institut de Química Teòrica i Computacional (IQTC) and Institut de Nanociència i Nanotecnologia (IN2UB), and Institució Catalana de Recerca i Estudis Avançats (ICREA), Universitat de Barcelona, Barcelona 08028, SpainSearch for more papers by this authorPedro Amorós Prof. Dr., Pedro Amorós Prof. Dr. Institut de Ciència dels Materials (ICMUV), Universitat de València, Paterna 46980, València, SpainSearch for more papers by this authorMiguel Julve Prof. Dr., Miguel Julve Prof. Dr. Departament de Química Inorgànica, Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna 46980, València, Spain, Fax: (+34) 963-544-859Search for more papers by this authorFrancesc Lloret Prof. Dr., Francesc Lloret Prof. Dr. [email protected] Departament de Química Inorgànica, Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna 46980, València, Spain, Fax: (+34) 963-544-859Search for more papers by this author First published: 09 May 2008 https://doi.org/10.1002/anie.200800208Citations: 41 † This work was supported by the Ministerio de Educación y Ciencia (MEC, Spain; projects CTQ2007-61690 and the Consolider-Ingenio in Molecular Science CSD2007-00010), the Ministère de l′Enseignement Supérieur et de la Recherche (MESR, France), the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES, Brazil; project COFECUB 460/04), and the Fundação de Amparo à Pesquisa do Estado de Minas Gerais (FAPEMIG, Brazil; projects CEX1837/06 and PRONEX 526/07). D.C., E.P., and M.C.D. thank the CAPES, the MEC, and the MESR/UPMC for grants. J.C. acknowledges the Universitat de València for an invited researcher grant. We are especially indebted to Dr. J.-M. Martínez and Dr. J. El Haskouri for thermogravimetric and gas sorption measurements, respectively. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Building a three-dimensional magnet: The manganese(II)-mediated self-assembly of a ferromagnetically coupled dicobalt(II) metallacryptand provides the first example of an oxamato-bridged heterobimetallic ferrimagnet with a three-dimensional honeycomb open-framework structure hosting linear arrays of water-bridged lithium(I) guests (see picture; mpba=1,3-phenylenebis(oxamato)). References 1M. Pilkington, S. Decurtins in Comprehensive Coordination Chemistry II: From Biology to Nanotechnology, Vol. 7 (Eds.: ), Elsevier, Oxford, 2004, p. 177. 2aM. Verdaguer, A. Bleuzen, V. Marvaud, J. Vaissermann, M. Seuleiman, C. Desplanches, A. Scuiller, C. Train, R. Garde, G. Gelly, C. Lomenech, I. Rosenman, P. Veillet, C. Cartier, F. Villain, Coord. Chem. Rev. 1999, 190–192, 1023; 2bM. Ohba, H. Okawa, Coord. Chem. Rev. 2000, 198, 313; 2cL. M. C. Beltran, J. R. Long, Acc. Chem. Res. 2005, 38, 325; 2dR. Lescouëzec, L. M. Toma, J. Vaissermann, M. Verdaguer, F. S. 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