Solid state supramolecular assemblies of charged supermolecules (Na[2.2.2]cryptate)+ and anionic carboranes with host cyclotriveratrylene
2001; Royal Society of Chemistry; Issue: 10 Linguagem: Inglês
10.1039/b009581h
ISSN1364-548X
AutoresMichaele J. Hardie, Colin L. Raston,
Tópico(s)Crystallography and molecular interactions
ResumoThe complex {(Na[2.2.2]cryptate)[CTV][Co(C2B9H11 )2]}2- (MeCN) (CTV = cyclotriveratrylene) features (Na[2.2.2]cryptate)+∩CTV interplay as well as a closely packed chain of [Co(C2B9H11)2]− counter-anions exhibiting dihydrogen bonding, and a similar cation–CTV assembly is found in (Na[2.2.2]cryptate)[CTV](CHCl3)3[CB11H 12].
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