New Motifs in Aurophilic Self‐Assembly: Synthesis and Structures of [Au(NHCMe 2 ) 2 ]CF 3 SO 3 and [Au(CCSiMe 3 )(CN t Bu)]
1997; Wiley; Volume: 36; Issue: 11 Linguagem: Inglês
10.1002/anie.199712031
ISSN1521-3773
AutoresJosé Vicente, M.T. Chicote, María‐Dolores Abrisqueta, Rita Guerrero, Peter G. Jones,
Tópico(s)Synthesis and characterization of novel inorganic/organometallic compounds
ResumoTwo new types of gold–gold interactions are described. Crystals of 1 contain polymeric chains with short contacts between cationic gold centers, while in 2 one gold atom is coordinated nearly trigonally by three others.
Referência(s)