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(C 4 N 2 H 12 )[Fe II 0.86 Fe III 1.14 (HPO 3 ) 1.39 (HPO 4 ) 0.47 (PO 4 ) 0.14 F 3 ]: A Fluoro–Phosphite–Hydrogenphosphate–Phosphate Iron( II , III ) Mixed‐Valence Organically Templated Compound

2004; Wiley; Volume: 43; Issue: 8 Linguagem: Inglês

10.1002/anie.200352219

1521-3773

Sergio Fernández‐Armas, José L. Mesa, J.L. Pizarro, J. S. Garitaonandía, M.I. Arriortua, Teófilo Rojo,

Inorganic Chemistry and Materials

Angewandte Chemie International EditionVolume 43, Issue 8 p. 977-980 Communication (C4N2H12)[FeII0.86FeIII1.14(HPO3)1.39(HPO4)0.47(PO4)0.14F3]: A Fluoro–Phosphite–Hydrogenphosphate–Phosphate Iron(II,III) Mixed-Valence Organically Templated Compound† Sergio Fernández-Armas Dr., Sergio Fernández-Armas Dr. Departamento de Química Inorgánica, Facultad de Ciencias, Universidad del País Vasco, Apdo. 644, 48080 Bilbao, Spain, Fax: (+34) 94-464-8500Search for more papers by this authorJosé L. Mesa Dr., José L. Mesa Dr. [email protected] Departamento de Química Inorgánica, Facultad de Ciencias, Universidad del País Vasco, Apdo. 644, 48080 Bilbao, Spain, Fax: (+34) 94-464-8500Search for more papers by this authorJosé L. Pizarro Dr., José L. Pizarro Dr. Departamento de Mineralogía-Petrología, Universidad del País Vasco, Apdo. 644, 48080 Bilbao, SpainSearch for more papers by this authorJosé S. Garitaonandia Dr., José S. Garitaonandia Dr. Departamento de Física Aplicada II, Universidad del País Vasco, Apdo. 644, 48080 Bilbao, SpainSearch for more papers by this authorMaría I. Arriortua Prof., María I. Arriortua Prof. Departamento de Mineralogía-Petrología, Universidad del País Vasco, Apdo. 644, 48080 Bilbao, SpainSearch for more papers by this authorTeófilo Rojo Prof., Teófilo Rojo Prof. [email protected] Departamento de Química Inorgánica, Facultad de Ciencias, Universidad del País Vasco, Apdo. 644, 48080 Bilbao, Spain, Fax: (+34) 94-464-8500Search for more papers by this author Sergio Fernández-Armas Dr., Sergio Fernández-Armas Dr. Departamento de Química Inorgánica, Facultad de Ciencias, Universidad del País Vasco, Apdo. 644, 48080 Bilbao, Spain, Fax: (+34) 94-464-8500Search for more papers by this authorJosé L. Mesa Dr., José L. Mesa Dr. [email protected] Departamento de Química Inorgánica, Facultad de Ciencias, Universidad del País Vasco, Apdo. 644, 48080 Bilbao, Spain, Fax: (+34) 94-464-8500Search for more papers by this authorJosé L. Pizarro Dr., José L. Pizarro Dr. Departamento de Mineralogía-Petrología, Universidad del País Vasco, Apdo. 644, 48080 Bilbao, SpainSearch for more papers by this authorJosé S. Garitaonandia Dr., José S. Garitaonandia Dr. Departamento de Física Aplicada II, Universidad del País Vasco, Apdo. 644, 48080 Bilbao, SpainSearch for more papers by this authorMaría I. Arriortua Prof., María I. Arriortua Prof. Departamento de Mineralogía-Petrología, Universidad del País Vasco, Apdo. 644, 48080 Bilbao, SpainSearch for more papers by this authorTeófilo Rojo Prof., Teófilo Rojo Prof. [email protected] Departamento de Química Inorgánica, Facultad de Ciencias, Universidad del País Vasco, Apdo. 644, 48080 Bilbao, Spain, Fax: (+34) 94-464-8500Search for more papers by this author First published: 11 February 2004 https://doi.org/10.1002/anie.200352219Citations: 44 † This work was financially supported by the Ministerio de Educación y Ciencia (PB97-0640; BQU2001-0678) and Universidad del País Vasco/EHU (9/UPV00169.310-13494/2001; 9/UPV00130.310-13700/2001), which we gratefully acknowledge. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract Site insights: The title compound has been synthesized by mild hydrothermal conditions. The iron(II) and iron(III) cations are trapped in two different crystallographic positions, whereas the phosphite and hydrogenphosphate–phosphate oxoanions are disordered in two phosphorus sites (see structure). The compound has antiferromagnetic interactions and the nature of the iron centers is investigated by Mössbauer spectroscopy. Citing Literature Volume43, Issue8February 13, 2004Pages 977-980 RelatedInformation