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Superior performance in deep saturation of bulky aromatic pyrene over acidic mesoporous Beta zeolite-supported palladium catalyst

2007; Elsevier BV; Volume: 249; Issue: 1 Linguagem: Inglês

10.1016/j.jcat.2007.03.031

1090-2694

Tiandi Tang, Chun‐Yang Yin, Liang Wang, Yuan Ji, Fan Xiao,

Nanomaterials for catalytic reactions

Palladium species were loaded into mesoporous Beta zeolite (Beta-H), and transmission electron microscopy images showed that the Pd particles are located in both mesopores and micropores. As a model reaction, the deep hydrogenation of bulky aromatic pyrene showed that the Pd/Beta-H catalyst exhibits higher activity than Pd/Beta, Pd/Al-MCM-41, and Pd/γ-Al2O3 catalysts. The superior performance of the Pd/Beta-H catalyst is attributed to its unique porous structure and acidity. The mesoporous volume in Beta-H (0.17 cm3/g) is greater than that of Beta (0.06 cm3/g), which is advantageous for adsorption and mass transport of pyrene over Pd/Beta-H catalyst. The amount of acidic sites is greater on Beta-H (480 μmol/g) than on Al-MCM-41 (280 μmol/g) and γ-Al2O3 (220 μmol/g), which also favors improved catalytic activity in hydrogenation of pyrene over Pd/Beta-H catalyst.