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Metal–Organic Frameworks from Edible Natural Products

2010; Wiley; Volume: 49; Issue: 46 Linguagem: Inglês

10.1002/anie.201002343

1521-3773

Ronald A. Smaldone, Ross S. Forgan, Hiroyasu Furukawa, Jeremiah J. Gassensmith, Alexandra M. Z. Slawin, Omar M. Yaghi, J. Fraser Stoddart,

X-ray Diffraction in Crystallography

Let them eat MOFs: Take a spoonful of sugar (γ-cyclodextrin to be precise), a pinch of salt (most alkali metal salts will suffice), and a swig of alcohol (Everclear fits the bill), and you have a robust, renewable, nanoporous (Langmuir surface area 1320 m2 g−1) metal–organic framework for breakfast (CD-MOF-1; see picture, C gray, O red, K purple; yellow sphere: pore). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.