Proline catalyzed aldol reactions in aqueous micelles: an environmentally friendly reaction system
2003; Elsevier BV; Volume: 44; Issue: 19 Linguagem: Inglês
10.1016/s0040-4039(03)00692-0
ISSN1873-3581
AutoresYiyuan Peng, Qiuping Ding, Zucheng Li, Peng George Wang, Jin‐Pei Cheng,
Tópico(s)Organic Chemistry Cycloaddition Reactions
ResumoThe proline catalyzed aldol reactions of nitrobenzaldehydes with various ketones in aqueous anionic micelles were investigated. Both the selectivities and reaction yields were observed to be higher than those of the corresponding reactions in organic solvents. A reaction mechanism is proposed that is somewhat different from that in organic solvents.
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