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Mild Rhodium(III)‐Catalyzed Direct CH Allylation of Arenes with Allyl Carbonates

2013; Wiley; Volume: 52; Issue: 20 Linguagem: Inglês

10.1002/anie.201301165

1521-3773

Honggen Wang, Nils Schröder, Frank Glorius,

Cyclopropane Reaction Mechanisms

All(yl) possible! A rhodium(III)-catalyzed intermolecular direct CH allylation reaction utilizing readily accessible allyl carbonates was developed. This method allows the allylation of electron-neutral arenes, providing complete γ-selectivity, high isomeric ratio, good substrate scope, and excellent functional group compatibility. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.