Stepwise Construction of Oligomeric 1,2‐Diselenolene Platinum( IV ) Complexes
2004; Wiley; Volume: 43; Issue: 31 Linguagem: Inglês
10.1002/anie.200453761
ISSN1521-3773
AutoresXavi Ribas, João Carlos Teixeira Dias, Jorge Morgado, Klaus Wurst, Manuel Almeida, Teodor Parella, Jaume Veciana, Concepció Rovira,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoSurrounded by selenium: Pulse field gradient spin-echo (PGSE) NMR diffusion studies of a mixture of oligomeric 1,2-diselenolene PtIV complexes are performed to characterize the species in solution (see structure: n=0 (1), n=1 (2), n=2 (3); red Pt, green Se, blue N, gray C). The results are in accord with the single-crystal X-ray diffraction structures obtained for the chiral complexes {PtIVSe6} (1) and {PtIV2Se10} (2). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2004/z53761_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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