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Iminium ion catalysis: Use of the α-effect in the acceleration of the Diels–Alder reactionElectronic supplementary information (ESI) available: 1H NMR, 13C NMR, IR and MS spectra. See http://www.rsc.org/suppdata/cc/b2/b212239a/

2003; Royal Society of Chemistry; Issue: 6 Linguagem: Inglês

10.1039/b212239a

1364-548X

Julie L. Cavill, Jens‐Uwe Peters, Nicholas C. O. Tomkinson,

Marine Sponges and Natural Products

The alpha-effect can be used in the acceleration of the Diels-Alder reaction between a series of dienes and electron deficient dienophiles using iminium ion catalysis, providing a novel molecular scaffold capable of performing this class of catalytic process.