Electric Control of Magnetization and Interplay between Orbital Ordering and Ferroelectricity in a Multiferroic Metal–Organic Framework
2011; Wiley; Volume: 50; Issue: 26 Linguagem: Inglês
10.1002/anie.201101405
ISSN1521-3773
AutoresAlessandro Stroppa, Prashant K. Jain, Paolo Barone, Martijn Marsman, J. M. Perez‐Mato, Anthony K. Cheetham, Harold W. Kroto, Silvia Picozzi,
Tópico(s)Magnetic and transport properties of perovskites and related materials
ResumoAngewandte Chemie International EditionVolume 50, Issue 26 p. 5847-5850 Communication Electric Control of Magnetization and Interplay between Orbital Ordering and Ferroelectricity in a Multiferroic Metal–Organic Framework† Dr. Alessandro Stroppa, Corresponding Author Dr. Alessandro Stroppa [email protected] CNR-SPIN, L'Aquila (Italy) Alessandro Stroppa, CNR-SPIN, L'Aquila (Italy) Prashant Jain, Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306 (USA)Search for more papers by this authorDr. Prashant Jain, Corresponding Author Dr. Prashant Jain [email protected] Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306 (USA) Alessandro Stroppa, CNR-SPIN, L'Aquila (Italy) Prashant Jain, Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306 (USA)Search for more papers by this authorDr. Paolo Barone, Dr. Paolo Barone CNR-SPIN, L'Aquila (Italy)Search for more papers by this authorDr. Martijn Marsman, Dr. Martijn Marsman University of Vienna, Faculty of Physics and Center for Computational Materials Science (Austria)Search for more papers by this authorProf. Juan Manuel Perez-Mato, Prof. Juan Manuel Perez-Mato Departamento de Fisica de la Materia Condensada, Facultad de Ciencia y Tecnologia, UPV/EHU, Bilbao (Spain)Search for more papers by this authorProf. Anthony K. Cheetham, Prof. Anthony K. Cheetham Department of Materials Science and Metallurgy, University of Cambridge (UK)Search for more papers by this authorProf. Harold W. Kroto, Prof. Harold W. Kroto Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306 (USA)Search for more papers by this authorDr. Silvia Picozzi, Dr. Silvia Picozzi CNR-SPIN, L'Aquila (Italy)Search for more papers by this author Dr. Alessandro Stroppa, Corresponding Author Dr. Alessandro Stroppa [email protected] CNR-SPIN, L'Aquila (Italy) Alessandro Stroppa, CNR-SPIN, L'Aquila (Italy) Prashant Jain, Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306 (USA)Search for more papers by this authorDr. Prashant Jain, Corresponding Author Dr. Prashant Jain [email protected] Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306 (USA) Alessandro Stroppa, CNR-SPIN, L'Aquila (Italy) Prashant Jain, Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306 (USA)Search for more papers by this authorDr. Paolo Barone, Dr. Paolo Barone CNR-SPIN, L'Aquila (Italy)Search for more papers by this authorDr. Martijn Marsman, Dr. Martijn Marsman University of Vienna, Faculty of Physics and Center for Computational Materials Science (Austria)Search for more papers by this authorProf. Juan Manuel Perez-Mato, Prof. Juan Manuel Perez-Mato Departamento de Fisica de la Materia Condensada, Facultad de Ciencia y Tecnologia, UPV/EHU, Bilbao (Spain)Search for more papers by this authorProf. Anthony K. Cheetham, Prof. Anthony K. Cheetham Department of Materials Science and Metallurgy, University of Cambridge (UK)Search for more papers by this authorProf. Harold W. Kroto, Prof. Harold W. Kroto Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306 (USA)Search for more papers by this authorDr. Silvia Picozzi, Dr. Silvia Picozzi CNR-SPIN, L'Aquila (Italy)Search for more papers by this author First published: 25 May 2011 https://doi.org/10.1002/anie.201101405Citations: 237 † This research was funded by the European Research Council under the European Community, 7th Framework Programme (2007–2013)/ERC Grant Agreement no. 203523. Computational support by CASPUR Supercomputing Center in Rome through "Standard HPC Grant 2010" is gratefully acknowledged. A.S., P.B., and S.P. wish to thank D. Khomskii for his careful reading of the manuscript and helpful insights. A.S. greatly acknowledges the visiting period at University of the Basque country in Bilbao, where part of this work was carried out, and the warm hospitality of the members of this institute. A.S. thanks F. De Angelis and M. Aschi (University of L'Aquila) for useful discussions. H.W.K. and P.J. thank the FSU Research Foundation for support. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Forget me not: In a new multiferroic metal–organic framework (see structure, Cu green, O red, C black, N blue, H gray; arrows show spin configuration), Jahn–Teller and antiferro-distortions induce a switchable ferroelectric polarization, which is coupled to a weak ferromagnetic component. This true magnetoelectric multiferroic should be very attractive for advanced memory devices. Citing Literature Volume50, Issue26June 20, 2011Pages 5847-5850 RelatedInformation
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